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Temperature Excursion in Environmental Chamber Results in Small Fire

Severity
Incident
Was Hydrogen Released?
Yes
Was There Ignition?
Yes
Incident Date
Incident Attributes
Setting
Damage and Injuries
Probable Cause
When Incident Was Discovered
Describe the incident, including corrective steps taken and their result.

A temperature excursion occurred in a sealed environmental chamber during a 0°C ambient temperature test. An elevated temperature in the chamber resulted in a small fire that was confined to the environmental chamber. Visual observation indicated no damage to nearby equipment, including nearby computer cables.

A committee was assembled with the task of identifying the cause of the incident. The committee concluded that the fire was caused by failure of the heater control system for the environmental chamber. The failure of the heater control system caused the chamber temperature to eventually exceed 200°C. As the chamber temperature increased, plastic materials and electrical insulation present in the chamber started to decompose. A battery scheduled for testing was also located in the chamber. As the temperature of the chamber rose, it is likely that water and possibly potassium hydroxide present in the individual cells of the battery components decomposed to yield hydrogen. At some point, these decomposition products ignited, caused either by the chamber temperature exceeding the ignition temperature or by sparks due to shorting of the electrical leads.

A subcommittee reviewed the electrical schematic and instruction manual for the environmental chamber. This group then energized the chamber to observe and troubleshoot the components crucial to temperature control and over-temperature protection. This was done by trained personnel using safe electrical "hot" work practices and appropriate lockout/tag-out procedures. Testing with the main power on, a simulated temperature was generated to exceed the set point for shut down of the heaters to the chamber. During this testing, it was observed that the over-temperature pilot light illuminated at the set point; however, the trip coil on the circuit breaker did not energize and, thus, did not shut down the chamber. It was clear at this point that there were two failures in the control circuitry; prior to the failure of the circuit breaker, there should have been a shutdown of the temperature control system. Further investigation identified a failure in the temperature controller card, allowing the chamber heaters to come on and stay on. Testing indicates that the chamber does operate, and with replacement of these failed parts, would operate properly.

Lessons Learned

The manufacturer will be notified of the failed parts identified as a result of the follow-up testing plan. These results may be useful to them for their information and forwarding to others with the same equipment.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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