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Storage Tank LFL Analyzer Reading Out of Surveillance Limits

Severity
Non-Event
Was Hydrogen Released?
No
Was There Ignition?
No
Incident Date
Incident Attributes
Damage and Injuries
Probable Cause
Contributing Factors
When Incident Was Discovered
Describe the incident, including corrective steps taken and their result.

As a prerequisite to a storage tank slurry pump run, a tank operator identified a Lower Flammability Limit (LFL) Analyzer surveillance reading to the control room that was out of limits low. The reading was a negative zero % LFL indication (-0 % LFL). The tank operator roundsheet limits are 0 to 10% LFL. The "null" value (value read on analyzer when air with 0% LFL is drawn through the analyzer) as directed by the LFL Analyzer loop calibration procedure is set between 0 and 4% LFL.

To alert personnel to the buildup of potentially dangerous levels of explosive gases in the tank, a Combustible Gas Detection System is used to monitor and analyze sample air drawn from the tank vapor space. This system consists of a sensing element, a 4-20 milliAmp direct current (mADC) output transmitter and a single channel controller. The indicating range of this unit is 0-100% LFL indication which corresponds to 0-100% of span and 4-20 mADC transmitter output.

A review of vendor documentation found that the tank analyzer transmitter output can be affected by ambient temperature changes. The manufacturer specifies a zero shift of 0.02% LFL indication per degree celsius change. Vendor documents also stated that a transmitter output signal of less than four milliamps (+/- 2%) is displayed as a negative % LFL reading. (Whenever the transmitter output is less than 4.05 mADC, it is displayed as a negative % LFL indication.)

The tank LFL Analyzer sensor and transmitter are located in an insulated cabinet in which the temperature is controlled at a nominal 37.8 degrees celsius. When the analyzer "null" value was adjusted to correspond to a 4.091 mADC transmitter output, the cabinet doors were open. With the cabinet doors open, the transmitter was subjected to the ambient outside temperature, which at that time was approximately 22.8 degrees celsius. When the negative zero indication was reported, the cabinet doors were closed and the cabinet temperature was being controlled at 37.8 degrees celsius. Due to the specified zero shift per degree celsius change, the 15 degree change in temperature resulted in the transmitter milliamp output decreasing enough to cause a negative zero meter indication.

Lessons Learned

This incident highlights the need to ensure that the performance of special procedures does not place facility equipment in a condition that could lead to entry into a LCO.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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