A pinhole at the base of a hand-held hydrogen torch, allowed hydrogen to leak. In the process of lighting a second torch, the leaking hydrogen was ignited. The operator, being startled by the "pop" of the lighted hydrogen allowed the #2 torch to drop and hang by its hose support approximately 6" from the floor. The hydrogen and oxygen hoses on the #1 torch were burned through and hung approximately 12" from the floor. The free burning #1 hose burned the #2 hydrogen and oxygen hose assembly through, causing both hoses assemblies to burn without valve control.
A waste pretreatment tank operator was performing surveillance rounds on a tank and found the Composite Lower Flammability Limit (CLFL) Analyzer sample flow reading 1.4 cubic feet per hour (CFH). The Operational Safety Requirements (OSR) document required flow range is 1.5 CFH to 2.5 CFH. The Limiting Condition for Operation was immediately entered and the tank operator adjusted the flow into the required surveillance range.
As a prerequisite to a storage tank slurry pump run, a tank operator identified a Lower Flammability Limit (LFL) Analyzer surveillance reading to the control room that was out of limits low. The reading was a negative zero % LFL indication (-0 % LFL). The tank operator roundsheet limits are 0 to 10% LFL. The "null" value (value read on analyzer when air with 0% LFL is drawn through the analyzer) as directed by the LFL Analyzer loop calibration procedure is set between 0 and 4% LFL.
A deficiency was discovered in the application of a hydrogen sensor in the Rotary Mode Core Sampling (RMCS) portable exhauster. The sensor is installed in the flow stream of the exhauster designed to be used with a RMCS truck for core sampling of watch list tanks, and is part of the flammable gas detector system. During the previous week, a quarterly calibration of the sensor, per maintenance procedure, was attempted by Characterization Project Operations (CPO) technicians. Ambient temperatures during the sensor calibration were approximately 20 to 30 degrees F.
A process area alarm activated. The alarm was caused by an instrument channel located above a reaction vessel off-gas system final HEPA filter canister, which indicated 25% of the lower explosive limit (LEL) for hydrogen. Since the only source of hydrogen is from the reaction vessel during the reaction of sodium with concentrated sodium hydroxide, the immediate actions were to shutdown the reaction process and place the facility in a safe condition.
A hydrogen monitor leak detector (HMLD) was out of service because of a failed membrane. The HMLD heater circuit and the ion pump and its associated controller were de-energized and red-tagged to ensure the system remained shut down. The ion pump and controller were later found energized. The ion pump circuit is a low-power (120-V, 1 amp) circuit and the pump operates in the micro-amp range. There was no damage to equipment from this inadvertent energization.
An unplanned shutdown of the hydrogen supply system occurred, affecting the hydrogen furnaces in the plant. The apparent cause was an inadvertent valve closing, which was contrary to the written procedure.
A facility representative observed pipe-fitters enter a containment tent around a riser with a tool bag that contained a mixture of steel and copper/beryllium tools. The top flange was loosened using a copper/beryllium socket and a steel torque wrench. When questioned, the pipe-fitters correctly stated that this was allowable for initial loosening and tightening of these bolts. A copper/beryllium ratchet was used to accomplish the bolt removal. The bonded riser was shifted to allow access for the IH technician.
Saltwell Pump May Have Been Operated While the Standard Hydrogen Monitoring System was Not in Operational Mode
One morning a saltwell pump was placed in operation. Operation of this equipment requires that the Standard Hydrogen Monitoring System (SHMS) cabinet be in operation. Later that morning, during the morning surveillance rounds, the Standard Hydrogen Monitoring System (SHMS) cabinet was found not to be in the operational mode.
Liquid Waste Disposition Projects (LWDP) has experienced repetitive events involving Hydrogen Monitor/LFL Analyzer degradations over the last year. There have been 12 reportables in the last two years. As a result, a determination was made to issue a recurring occurrence report referencing management concern as its reporting criteria.