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Hydrogen Gas Leak from Compressed Gas Cylinder

Severity
Incident
Was Hydrogen Released?
Yes
Was There Ignition?
No
Incident Date
Incident Attributes
Setting
Damage and Injuries
Probable Cause
When Incident Was Discovered
Lessons Learned

LESSONS LEARNED:

Compressed gas cylinder caps can be very difficult to open as rust often occurs in the threads.
There are wrenches specifically designed to remove compressed gas cylinder caps. The lab had such a wrench and it was the one used by staff at the time of the incident. (See attached photos.)
The wrench designed for the cylinder caps is short and often does not provide enough leverage to easily open the cylinder caps. Staff indicated that they often reverse the wrench, pushing it through one of the cylinder cap openings to gain additional leverage on cylinder cap lids. They indicated this was a common practice with exceptionally difficult cylinder cap lids and they did not believe it could interfere with the cylinder valve.
The training program did not prohibit using the valve cap wrench in the manner it was used.
The cylinder was empty when it was received by the hydrogen supplier. The valve and pressure relief device did not show any leaks when the cylinder was pressurized with helium. The supplier believes that on the day of the incident, the cylinder valve was bumped open with the wrench used to remove the cap.
Other laboratory staff noted that they only heard part of the page to evacuate the lab due to background noise in their labs, but they did evacuate immediately anyway.
The company maintains written descriptions of how to safely handle compressed gas cylinders in their job safety analysis sheets and their safe work practices handbook. Neither reference prohibited the valve cap wrench being used in the manner it was.
Visual inspection of the analytical lab was done to confirm that all staff had exited the laboratory, but formal written accountability was not conducted.
Facilities staff determined that it was not possible to adjust air flow within the analytical lab from outside the lab because all the controls are located inside the lab.

CORRECTIVE ACTIONS:

Obtain different wrench that provides adequate torque on cylinder cap, but cannot interfere with valve.
Train staff on how to use new wrench.
Have staff loosen cylinder caps outside of the building before bringing the cylinder into the lab.
Install cylinder station outside of the building to hold cylinders with difficult-to-open cylinder caps.
Update job safety analysis sheet to reflect new cylinder handling procedures.
Emergency pages should be made twice. For any event that could lead to a fire or explosion, staff should immediately evacuate the area and pull the closest fire alarm box.
Share lessons learned with other facilities.
Reinforce with staff the need to check offices, conference rooms, and rest rooms as they are evacuating to ensure that all staff are aware of the emergency.
Reinforce with incident commanders the need to ensure that formal written accountability is taken during an emergency.
Investigate the feasibility of relocating critical building controls outside of the analytical lab.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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