A rupture disc blew on a 20,000-gallon liquid hydrogen tank, causing the vent stack to exhaust cold gaseous hydrogen. Emergency responders were called to the scene. To stabilize the tank, the remaining hydrogen was removed from the tank except for a small volume in the heel of the tank that could not be removed manually. The tank vacuum was lost. Firemen sprayed the tank with water and directed a stream onto the fire exiting the vent stack. The water was channeled directly into the open vent stack, and the exiting residual hydrogen gas (between -423 F and -402 F) caused the water in the vent stack to freeze. The water freezing caused the vent stack to be sealed off, disabling the only exit for the cold hydrogen gas. After a time, the residual hydrogen gas in the tank warmed up, causing view more

Several parties were involved in hydrogen quality sampling when it was discovered that a hose which was being used in the collection process, connecting two sampling components, was not rated for the pressure to which it was being subjected. Upon discovery, the process was stopped, the hose was removed, and an alternate configuration of the equipment was implemented before carrying on the sampling.

An isolated vehicle hydrogen tank needed to be de-fueled, but the standard operating procedure could not be followed because the tank was inoperable and had to be manually vented with a special tool. This intentional release of hydrogen was done outside an R&D facility, but it unintentionally activated two sensors on vehicle bay gas detectors (at 20% LFL) in the adjacent indoor facility. Although each person involved in this activity was qualified to perform the work, the circumstances at the time were unusual.

During maintenance on a breakaway fitting, a review of the pressure rating of the adapter fitting connecting the pipe to the breakaway found the adapter to be under rated for the design pressure. While the male straight-thread side of the "standard" fitting was rated to 7700 psig, the female compression-tube end of the same fitting was rated to only 4900 psig. The adapter was replaced with a fitting of increased wall thickness meeting the design pressure rating.

The cap on a full cylinder of hydrogen was difficult to remove. A wrench was applied to turn the cap. When the cap was turned, a part of the wrench contacted the valve and opened it. Since the cap was still on the cylinder, the valve could not be closed. The area was evacuated until the cylinder had emptied.

A fatal accident took place at an onshore processing facility for slop water from the offshore petroleum industry.

Drilling fluids, or mud, are typically oil-water emulsions consisting of base oil (continuous phase), water (dispersed phase), and emulsifying agents. Used drilling mud, or slop, is mud enriched with water and rock cuttings from drilling --- typically 60-80% water, 10-20% emulated base oil, and 10-20% rock cuttings. The used drilling fluids are collected in slop tanks on oil platforms and later shipped to onshore facilities for further processing.

On the day of the accident, two operators were trying to remove the lid from a manhole on top of a 1600-cubic meter storage tank. However, they were not able to unscrew the rusted bolts holding the lid in place, and view more

Hydrogen was released near the ground when the vent line from a 13,000-gallon liquid hydrogen storage vessel suffered damage from unusually high winds. The toppled vent line did not shear or tear, but sustained a kink that restricted hydrogen flow and created a back pressure on the vessel relief system.

Repair efforts were hampered by the potential for cold hydrogen gas, a flammability hazard, in the work area. Shut off or redirection of the hydrogen was not possible, and variable breezes made set up of safe zones uncertain. A protocol had not been prepared for this scenario.


A steel tube with inner diameter of 6 mm and 10 m length was filled with radiolysis gas (stoichiometric H2-O2 mixture) at 70 bar for boiling water reactor simulations. Via a pneumatic valve, a venting line with similar cross-section and 2 m length, filled with atmospheric air, was connected.

For venting the tube, the valve was opened (fast) and an explosion occurred.

Explanation: Due to diffusion ignition in the leading shock, a flame flashed back into the pre-mixed reservoir and induced a detonation there. The tube system and involved measurement technique was destroyed. For safety reasons, the whole installation was set up in a protective container so that no person or other equipment was threatened.

A pressure relief device (frangible burst disk) on one of a hydrogen delivery tube trailer's 26 tubes failed prematurely and released hydrogen while filling a hydrogen storage tank at a government facility (see Attachment 1). Prior to the filling process, all procedures and safety checks, including connection to the facility's regulator/distribution control system with leak checking and follow-up verification of leak checking by facility personnel, were completed (see Attachment 2 for more details). During the filling process, a person walking near the facility heard the noise of escaping gas that included occasional popping sounds typical of bursts of gas release. Facility personnel were alerted and the tube trailer vendor's incident response team was dispatched to the view more

Two scientists were changing hydrogen gas cylinders in an analytical laboratory. They were in the process of removing the cylinder cap from the new cylinder when a loud hissing noise occurred and they quickly realized that the tank was leaking. After making a quick attempt to shut off the tank, which was not possible, they left the lab and notified their supervisor.

After checking that everyone was out of the lab, the supervisor paged all staff in the vicinity to immediately evacuate to the staging area. Facility management and ES&H management were notified about the situation, and they contacted the local fire department to respond to the site in case the venting gas was ignited.

The first responders arrived quickly and spoke with facility management and the site view more