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Organic Vapor Ignites When Hydride Decomposes in Air

Severity
Incident
Was Hydrogen Released?
Yes
Was There Ignition?
Yes
Incident Date
Ignition Source
reactive hydride exposed to air
Incident Attributes
Setting
Equipment
Damage and Injuries
When Incident Was Discovered
Describe the incident, including corrective steps taken and their result.

An experienced researcher with 30+ years of laboratory experience (including working with air-sensitive compounds) was disposing of a small vial of catalyst and hydride powder left in the laboratory by a post-doc. The researcher emptied the vial into a container of mineral oil inside a glove box, but a small amount of the hydride powder adhered to the wall of the vial. The vial was then removed from the glove box and brought over to a tall waste jar in the laboratory that contained isopropanol. (Isopropanol is the first (slowest-acting) pacifier used when deactivating pyrophoric hydrides.) The vial was opened and inverted over the isopropanol jar and the residue powder was tapped into the jar. There was a "small flash of flame" that quickly extinguished itself.

Lessons Learned

The project team concluded that the jar contained a sufficient vapor pressure of isopropanol to ignite when it came into contact with the decomposing hydride. The lesson learned was that hydrides react rapidly in air and can lead to combustion of any organic vapor that might be present nearby. Thus, the project team adopted a procedure that all hydrides must be submerged in mineral oil before they are removed from the glove box to prevent exposure to air before isopropanol treatment. Since this procedure was adopted for pacification/disposal of hydrides, there have been no more incidents or near-misses of this type in the laboratory.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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