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Degradation of Safety-Significant Valve

Severity
Near-Miss
Was Hydrogen Released?
Uncertain
Was There Ignition?
No
Incident Date
Incident Attributes
Equipment
Damage and Injuries
Probable Cause
Contributing Factors
When Incident Was Discovered
Describe the incident, including corrective steps taken and their result.

The valve stem for a funnel valve to a solution neutralization tank was found to be separated from the body of the valve. This valve is used for purging hydrogen gas from the vessel. The functional classification of this valve is safety-significant. The "as-found" condition of the affected valve prevented the valve from performing its intended design function.

The affected valve is a one-half inch polyvinyl chloride (PVC) ball valve. The valve has an extension shaft coupled to the valve body, and the valve handle is coupled to the extension shaft, allowing the valve to be operated outside the process panel cover. The valve stem is cross-drilled and the extension shaft is pinned through the stem.

With this occurrence, engineering evaluated the one-half inch PVC ball valve design, and redesigned the extension rod and handle, which will be installed when the affected valve is replaced. The redesign will allow replacement of the extension rod and handle without requiring removal of the valve itself. The redesigned extension and valve handle will apply lower operating stresses to the valve stem, minimizing the likelihood of recurrence.

Lessons Learned

This occurrence demonstrated the use of data by engineering to evaluate equipment problems. As the data changed, highlighting a problem with one-half inch PVC ball valves, the facility redesigned the valve extension and valve handle to prevent recurrence.

Valves for compressed gas service and for cryogenic liquid service are discussed in the Hydrogen Safety Best Practices Manual.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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