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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Explosion During Hydrogen Delivery in a Power Plant
A hydrogen explosion occurred at a 585-MW coal-fired supercritical unit and caused one fatality, injuries to 10 other people, and significant damage to several buildings. The explosion occurred during a routine delivery of hydrogen when a hydrogen relief device failed, which allowed the contents of the hydrogen tank to escape and be ignited by an unknown source. The truck driver was delivering hydrogen gas to fill two 6500 cubic feet storage cylinders at the plant. The hydrogen gas was used to cool the generator at the power plant. At approximately 9:22 a.m., the employer, who was working alone at the time, was in the final stages of filling the cylinders. At this time witnesses heard a loud noise, like high pressure gas venting through a relief valve, and within 15 to 20 seconds, the hydrogen gas exploded, killing the employee and injuring eight co-workers. The investigation revealed that the hydrogen gas over pressurized a rupture disk attached to one of the hydrogen cylinders. As the set pressure of the rupture disk was between 3500 (24 MPa) and 4000 psi (28 MPa), and the maximum pressure that could have be put on the system during filling was 2600 psi (18 MPa), the rupture disk failed well below its designed pressure. The release of hydrogen through the relief vent piping, which terminated outside above the roof, also caused the copper vent tubing to fail and burst apart at a 45 degree elbow below the roof, therefore releasing hydrogen gas under the roof. This allowed the gas to accumulate into a large cloud that subsequently ignited and exploded. The force of the explosion killed the employee and injured nine AEP workers in an adjacent building.
Event Date
January 8, 2007
Record Quality Indicator
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
Immediate cause was the failure of a rupture disk well below its nominal rupture pressurePossible Root Cause was the replacement of rupture disk with another type. Contributing cause can be found in the possible ill design of the pipe supposed to release the gas above the roof, which failed with the consequence that the gas was released under the roof.
Facility Information
Application Type
Specific Application Supply Chain Stage
Components Involved
hydrogen storage system, cooling system of a power plant
Storage/Process Medium
Design Pressure
180
Location Type
Location description
Industrial Area
Operational Condition
Pre-event Summary
Hydrogen is used at the coal-fired power plant to cool the unit generators. The storage cylinders are filled once of twice per week by external contractor with a hydrogen trailer.The rupture disk on the storage tanks had been replaced by the hydrogen vendor several months prior, when the vendor was on-site to make repairs related to an apparent leak. The previous device was a fusible bismuth plug holding a coin-shaped disc in place until temperatures exceed 180 degrees. The replacement relief device assembly did not have a fusible plug to support the disc.
Consequences
Number of Injured Persons
3
Currency
Lessons Learned
Lessons Learned
Most of the OHSA conclusion were directed at the design and construction of the hydrogen system.In addition, the OHSA concluded that "The employer did not furnish employment and a place of employment, which were free from recognized hazards that were causing or likely to cause death or serious physical harm to employees. Precautions were not taken to prevent the ignition due to: (A) Failure to use non-sparking tools (crescent wrench) to open the hydrogen tube trailer main valve; (B) Failure to shut off the engine of the tractor delivering the tube trailer.A feasible and acceptable method of abatement would be to remove all potential ignition sources while transferring hydrogen gas from trailers to customer storage cylinders, including: 1. Use non-sparking tools while working on hydrogen gas equipment; 2. Shut down the engine of the tractor before initiating the transfer of hydrogen gas from the tube trailer to the storage cylinders."
Event Nature
Emergency Action
Local fire department and emergency medical technicians also quickly responded to the incident and assisted with emergency response and evacuation actions.The main activity has been to keep cool the hydrogen delivery truck and the surrounding area after the explosion.
Release Type
Release Substance
Hydrogen Release Concentration (%)
100.00
Release Pressure (bar)
180.00
Ignition Source
Ignition Delay (s)
20
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

POWER, News & Technology for the Global Energy Industry
Apr 30, 2009
Available at: https://www.powermag.com/lessons-learned-from-a-hydrogen-explosion/
(accessed July 2020)

Occupational Safety and Health Administration report
https://www.osha.gov/pls/imis/accidentsearch.accident_detail?id=2007583…
(accessed 2020)

WHA case study, available at
https://wha-international.com/case-study-power-plant-hydrogen-explosion/
(accessed May 2023)

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