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Explosion During Hydrogen Supply in a Chemical Company (1089)

This event occurred when a hydrogen-carrying trailer was supplying hydrogen to a chemical plant. Instead of filling the hydrogen stationary storage, large quantities of hydrogen were transferred from the trailer into the compressed air plant network. The explosive atmosphere ignited in a compressed air consumer (a solid silo which was not containing hazardous materials).

Release from the Storage of a Hydrogen Production Plant (1086)

The accidental hydrogen release occurred when testing the storage system connected to a PEM electrolyzer. The leak test consisted in filling the storage with hydrogen at step-wise increase of pressure. After the step at 3 bar (0.3 MPa), which did not reveal any leak, the storage was pressurised up to 5 bar (0.5 MPa). At that moment a hissing sound occurred from the storage at the outside of the building indicating a leak.

Explosion at an Electrolyzer at a Refueling Station (1084)

This incident occurred at the electrolyzer of a refuelling station. An employee of the electrolyzers manufacturer was on-site to conduct a reset of the plant power breaker system and to restart gas generation. Whilst putting the system into generation, a loud bang was heard. By reviewing the station CCTV evidence, a cloud of water vapour was seen being emitted from the oxygen vent line of the electrolyzer container. The gas generation system was safely shut down, and an investigation was started to understand the cause and potential impacts.

Highway Truck Crash and Fire (1081)

On a highway, a truck loaded with 400 gas cylinders crashed at night for an undetermined cause against a concrete wall and overturned. It slipped 150 m, before several 200 litre cylinders of hydrogen caught fire and set the truck on fire as well. The police stated that it was a large fire with detonations. The 400 gas cylinders were connected together and many of the cylinders had fallen out of their racks. In order to reduce the danger of further explosions, the fire-brigade cooled the gas cylinders with water for two hours. The highway remained closed for eight hours.

Explosion at a Water Treatment Facility (1080)

This incident occurred when subcontractor two workers were widening air vents on the roof of a building hosting a tank containing hydrogen chloride solution. This intervention was necessary to to improve hydrogen venting from the tank storage area. The hydrogen gas was a by-product of the chlorine-making process. The two workers were operating an angle grinder, producing sparks which ignited the flammable atmosphere which evidently containing hydrogen. An explosion followed, with one casualty and one injured worker.

Explosion in a Chlorine Production Plant (1075)

A lightning strike caused a voltage drop on the power supply of a chlorine-alkali plant using the mercury process.The emergency electrical system was activated, though restoring the external supply voltage in less than 200 ms rendered the entire system inconsistent; some units were operating normally, but all units connected to the emergency devices (including the mercury pump) remained idle. An explosive mix of 500 kg of chlorine and an unknown amount of hydrogen accumulated inside the low-pressure chlorine treatment circuit.

Blind Flange Connection Failure Causes Hydrogen Fire During Pipeline Inspection (1060)

An in-line inspection of the hydrogen pipeline was being conducted and prior to the last run of the in-line inspection tool (mfl), hydrogen gas was released and ignited from a blind flange connection failure on a temporary separator filter installed at the receiver site. The fire was immediately identified by on-site personnel. There were no injuries. The pipeline section was isolated and de-pressurised to the facility flare. Local emergency responders were dispatched and contained and extinguished the fire. The fire affected the station piping and equipment in the surrounding area.

Explosion of a Storage Vessel in a Hydrogen Production Facility (1053)

This incident occurred at the hydrogen production and storage unit of (probably) a power plant using hydrogen as a coolant of the turbine-generator system. Hydrogen was produced probably by water electrolysis (the source does not say it) and stored in 6 steel tanks. One of the six hydrogen storage tanks exploded killing a staff member. The investigation determined that a mixing of hydrogen and oxygen occurred in the tank. The needle valve of the hydrogen and oxygen pressure regulator as jammed, and the oxygen leaked into the hydrogen main supply line and entered the hydrogen tank.

Implosion/Explosion on a Furnace Copper Metallurgy Company (1026)

An implosion/explosion occurred on a furnace in a company of copper metallurgy. The incident occurred at the end of the production cycle, when the furnace bell is lifted at the end of the cooling process. The operator in charge of the lifting was thrown away and slightly burned in the face. The victim was evacuated and the emergency services were alerted. The building structures (windows, doors, roof) experienced serious damage. The power supply was switched off.

Hydrocarbons and Hydrogen Fire in a Refinery (1024)

At around 9:15 a.m., during a routine inspection, a flame was observed at the bottom flange of a reactor in a refinery. A few moments later, sensors near the leak detected a rise in temperature.The facility was shut down in accordance with emergency procedures. The sprinkler system was triggered to protect the equipment. The rapid decompression of the plant towards the safety flare reduced the leak flow rapidly. At 10:12 am, the fire was extinguished.
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