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Explosion in a Chlorine Production Plant (1075)

A lightning strike caused a voltage drop on the power supply of a chlorine-alkali plant using the mercury process.The emergency electrical system was activated, though restoring the external supply voltage in less than 200 ms rendered the entire system inconsistent; some units were operating normally, but all units connected to the emergency devices (including the mercury pump) remained idle. An explosive mix of 500 kg of chlorine and an unknown amount of hydrogen accumulated inside the low-pressure chlorine treatment circuit.

Natural Hydrogen Fire (1074)

In 1987, well diggers had drilled a well for water, but had given up on one dry borehole at a depth of 108 meters. According to the source reported in the References, wind was coming out of the hole. When one driller peered into the hole while smoking a cigarette, the so-called wind exploded in his face. A huge fire followed, without smoke, looking bluish at daytime and colour and goldish at night. The crew needed weeks before being able to stop the fire and cap the well. The well remained capped until 2007, when well gas was analysed and revealed to consist in hydrogen with a purity of 98%.

Hydrogen Leak and Fire in Compressor Area of Continuous Reforming Unit (1073)

A hydrogen leakage caught fire in the hydrogen compressor area of the continuous reforming unit. The reforming unit and the hydrocracking unit were immediately stopped. The hydrogen flow was cut off, a protective combustion was carried out and the fire was completely extinguished after approximately 20 minutes, with no casualties. The cause of the accident is being investigated.

Fire on a Hydrogen Bus During Refueling (1072)

The fire developed an early morning on a hydrogen bus at a refuelling station for public transport. The fire Department was called to site responding to reports of a fire on the property. A section of the highway was closed as firefighters.According to the bus company release, one bus was destroyed and the dispenser of the hydrogen fuelling station was damaged. The stationary hydrogen storage and the rest of the Explosions were heard and seen from the tanks on the bus that had just been filled.

Fire on a Hydrogen Vehicle Prototype (1071)

DISCLAIMER: this event description is unsatisfactory. Details on the system and the real incident evolution are (still) missing. The incident affected a prototype light hydrogen vehicle in a hydrogen research centre of a university. The vehicle was a kind of a four-wheeled scooter. The fire started on the vehicle while being filled. Apparently, the hydrogen storage system was a hydrogen hydride. The site was evacuated and the building isolated from its hydrogen supply. The firefighters attacked the fire with a hose and extinguished it one hour later.

Fire on a Hydrogen Compressor of Refinery (1070)

The broke out at a hydrogen compressor of the reforming unit of the refinery. Following the safety procedures, the emergency stop of the unit was activated and the unit was decompressed using a safety flare. The emergency plan was kept for an hour. A security perimeter is in place. The isolation of the compressor was started automatically. The isolation of the discharge circuit was successful, but the suction circuit could only be partially closed due to a block of a valve. The operators then closed manually the suction valve, by removing the excess of grease that had been applied to it.

Fire in the Electrical Transformer of a Metallurgical Plant (1068)

A fire broke out on a transformer transforming 225,000 V into 15,000 V in a metallurgical plant. This transformer supplies electrical power the site and to a neighbouring factory. In the following three hours, staff brought the fire under control with CO2 extinguishers, the internal emergency plan was activated, and the firefighters ventilated the premises and took readings of the flames using a thermal camera. Meanwhile, however, the shutdown of the electrical installation caused the stop of the operation of an electrolysis unit using zinc sulphate.

Fire in a Chemical Factory (1067)

A fire broke out following a hydrogen leak on the cyclododecane unit in a chemical plant. A plume of smoke became visible outside the site. The fire was brought under control by putttng the unit in safe mode, implementing the internal resources available on site (monitor lance, sprinkler ring and extinguishers), and finally by the inervention of the internal firefighters. The staff was evacuated and the internal crisis unit triggered. The fire was extinguished in 30 minutes. The post-incident analysis revealed a hole in the connection of the vent manifold, upstream of the evacuation pipe.

Fire on the Hydrodesulfurization Unit of a Refinery (1066)

Around 4 a.m., a major leak occurred at the outlet of the diesel hydrodesulfurization furnace in a refinery. The goal of this unit is to lower the sulfur content of diesel fuels produced in other units, by a catalytic reaction in the presence of hydrogen. At the moment of the leak the furnace was restarting. The alarms of the temperature sensors at the oven outlet were triggered. At 4:08 a.m., the operator shut down the hydrogen compressors and diesel charging pumps, closed the supply valves and called the emergency status. The first emergency operation was to decompress the unit.
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