Potential Un-reviewed Safety Question Due to Liquid Hydrogen Tank Installation

First Name
Andy
Last Name
Piatt

Installation of a 9000-gallon liquid hydrogen storage tank by a lessee at a building has not been evaluated for effect on the Safety Authorization Basis (SAB) of nearby facilities.

During review of an Emergency Management Hazard Assessment document, a reviewer questioned whether the SAB of nearby facilities had been reviewed for the effect of the installed 9000-gallon liquid hydrogen tank. Reviews by the facility management and facility safety personnel confirmed the evaluations have not been performed.

Hydrogen Purge Frequency Exceeded in Vessel

First Name
Andy
Last Name
Piatt

An operator went to purge a process tank per standard operating procedure. The operator reviewed the previous shift's purge time and determined the next required purge time. The operator found that the tank had been purged earlier than expected on the previous shift. Because the earlier purge time was not recognized, the 12-hour purge frequency was exceeded.

Non-Sparking Tools Used for Intrusive Work

First Name
Andy
Last Name
Piatt

A facility representative observed pipe-fitters enter a containment tent around a riser with a tool bag that contained a mixture of steel and copper/beryllium tools. The top flange was loosened using a copper/beryllium socket and a steel torque wrench. When questioned, the pipe-fitters correctly stated that this was allowable for initial loosening and tightening of these bolts. A copper/beryllium ratchet was used to accomplish the bolt removal. The bonded riser was shifted to allow access for the IH technician.

Hydrogen Fire in a Storage Vessel

First Name
Andy
Last Name
Piatt

In the fall of 2007, the operations team began a procedure (a written procedure was being followed) to sample the liquid hydrogen (LH2) storage vessels ("tanks"), and associated transfer system. This procedure was being performed to determine the conditions within the system, and if necessary, to purge the system of any excess gaseous hydrogen (GH2) in preparation for reactivation of the system. The system had not been used since 2003.

Hydrogen Fire from Valve Packing During Maintenance Shutdown at Chemical Manufacturing Plant

First Name
Andy
Last Name
Piatt

A chemical plant experienced a valve failure during a planned shutdown for maintenance that caused hydrogen to leak from a valve and catch fire. Four chemical reactor chambers in series were being emptied of liquid using hydrogen gas as part of a maintenance procedure. Two heater valves were opened allowing 3000 psi hydrogen to flow in reverse direction to purge the reactor system for approximately 25 minutes. At completion of the purging process, a "light" thud was heard as the reactor empty-out valves are being closed.

Partially spent ammonia borane reaction with water

First Name
Andy
Last Name
Piatt

As part of preparing for material disposal, a small fire occurred within a fume hood as a researcher was combining several spent ammonia borane (AB) samples that had previously been stored uncovered in the back of the hood for 6+ months. These AB samples consisted primarily of two 40-gram products of a 50wt% AB in silicone oil that had been thermally dehydrogenated. A small amount of unreacted AB slurry is believed to also have been present.

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