Incorrect Check Valve Installation

First Name
Andy
Last Name
Piatt

The contractor was replacing a needle valve and a check valve on the nitrogen purge line to the dispenser because of a small leak at the connection between the needle valve and the check valve. On reinstalling the valves, the contractor installed the check valve backwards, causing the pressure disk in the regulator to fail, venting about 1000 psig hydrogen into the air for about 10 seconds. This was found during testing of the contractor's work before the system was returned to normal service.

Low-Pressure Vent Line Leak

First Name
Andy
Last Name
Piatt

A hose clamp failed on a low-pressure vent line from a hydrogen reactor experiment and effluent was leaked into the laboratory. Unburnt hydrogen in the effluent stream triggered the low-level hydrogen alarm. The hose clamp was resecured and other hose clamps were checked for proper tightness.

Hydrogen Fire at an Aircraft Parts Manufacturing Facility

First Name
Andy
Last Name
Piatt

During normal operations, a two-inch flame was discovered emanating from a pinhole leak in a hydrogen line at an aircraft parts manufacturing facility. Hydrogen was not in use by any process in the facility at the time. The flame was discovered by a contractor who was about to start welding on scaffolding about 3-5 feet away. Before starting, the welder searched the immediate area for any signs of fire per his training. When he spotted the flame, he called his supervisor.

Hydrogen Tube Trailer Burst Disc Ruptures Prematurely While Filling

First Name
Andy
Last Name
Piatt

Near the end of the process of filling a gaseous hydrogen tube trailer at a liquid hydrogen transfilling station, a safety pressure-relief device (PRD) rupture disc on one of the tube trailer’s ten tubes burst and vented hydrogen gas. The PRD vent tube directed gas to the top of the trailer where the hydrogen vented and ignited, blowing a flame straight up in the air. The operator filling the tube trailer heard a loud explosion from the sudden release of hydrogen gas and saw flames immediately.

Hydrogen Vent Blow Down

First Name
Andy
Last Name
Piatt

Hydrogen was released near the ground when the vent line from a 13,000-gallon liquid hydrogen storage vessel suffered damage from unusually high winds. The toppled vent line did not shear or tear, but sustained a kink that restricted hydrogen flow and created a back pressure on the vessel relief system.

Repair efforts were hampered by the potential for cold hydrogen gas, a flammability hazard, in the work area. Shut off or redirection of the hydrogen was not possible, and variable breezes made set up of safe zones uncertain. A protocol had not been prepared for this scenario.

Hydrogen Fueling Dispenser Breakaway Adapter

First Name
Andy
Last Name
Piatt

During maintenance on a breakaway fitting, a review of the pressure rating of the adapter fitting connecting the pipe to the breakaway found the adapter to be under rated for the design pressure. While the male straight-thread side of the "standard" fitting was rated to 7700 psig, the female compression-tube end of the same fitting was rated to only 4900 psig. The adapter was replaced with a fitting of increased wall thickness meeting the design pressure rating.

Hydrogen Fire in Hydrochloric Acid Leaching Solution

First Name
Andy
Last Name
Piatt

Spent platinum catalyst is recovered from corrugated stainless steel by chemical stripping and recovery. The process is completed by placing the material in lined tanks filled with hydrochloric acid (HCl). Approximately 500 pounds of corrugated stainless steel with platinum coating was inserted into a HCl leaching bath. Prior to starting the process, the supervisor tested the material for reactivity for a period of one hour, and the material showed very little reactivity. Operators began setting up three 500-gallon tanks, each containing the corrugated material.

Hydrogen Leak from Onboard Storage System of a Fuel Cell-Powered Lift Truck

First Name
Andy
Last Name
Piatt

A significant hydrogen leak occurred during refueling of the onboard hydrogen storage tank of a fuel cell-powered lift truck while it was completely depowered. The in-tank shutoff solenoid valve had recently been replaced, and this was the initial refueling event after the replacement. The fuel zone access panel was removed to allow constant visual leak checking with Snoop leak-detection fluid. The event occurred during the final pressure testing of the repaired system when an O-ring failed at approximately 4500 psi, releasing the entire contents of the hydrogen tank in about 10 minutes.

Rupture of Refinery Heat Exchanger

First Name
Andy
Last Name
Piatt

A petroleum refinery experienced a catastrophic rupture at one bank of three heat exchangers in a catalytic reformer/naphtha hydrotreater unit because of high temperature hydrogen attack (HTHA). Hydrogen and naphtha at more than 500F were released from the ruptured heat exchanger and ignited, causing an explosion and an intense fire burned for more than three hours.

Pipe Ruptures during Hydrogen Regeneration of Catalyst

First Name
Andy
Last Name
Piatt

A distillate dewaxing unit at an oil refinery was undergoing hot hydrogen regeneration of the catalyst when an explosion occurred. Catalyst regeneration is a periodically performed procedure, in which the normal liquid hydrocarbon feed is stopped and a hydrogen-rich gas mixture is fed through the catalyst bed for which the normal operating temperature is raised from 700F to 800F. During the catalyst regeneration process the reactor pressure is increased from normal operating levels just below 600 psig to about 640 psig.

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