Failure of an Argon Check Valve

First Name
Andy
Last Name
Piatt

A facility replaced the copper tubing used for hydrogen distribution, with stainless steel tubing. This was done to address a fire protection concern related to the solder on the copper tubing being susceptible to heat, melting, and releasing a flammable gas. The facility maintenance personnel completed the replacement, noted the pressure on the hydrogen bottle, and left the building. When the maintenance person returned on the following day, s/he noticed the pressure on the hydrogen bottle had dropped 500 psi overnight, indicating a leak in the system.

Inadvertent Energizing of a Red-Tagged Circuit

First Name
Andy
Last Name
Piatt

A hydrogen monitor leak detector (HMLD) was out of service because of a failed membrane. The HMLD heater circuit and the ion pump and its associated controller were de-energized and red-tagged to ensure the system remained shut down. The ion pump and controller were later found energized. The ion pump circuit is a low-power (120-V, 1 amp) circuit and the pump operates in the micro-amp range. There was no damage to equipment from this inadvertent energization.

Non-Sparking Tools Used for Intrusive Work

First Name
Andy
Last Name
Piatt

A facility representative observed pipe-fitters enter a containment tent around a riser with a tool bag that contained a mixture of steel and copper/beryllium tools. The top flange was loosened using a copper/beryllium socket and a steel torque wrench. When questioned, the pipe-fitters correctly stated that this was allowable for initial loosening and tightening of these bolts. A copper/beryllium ratchet was used to accomplish the bolt removal. The bonded riser was shifted to allow access for the IH technician.

Improper Purging Procedure Results in Hydrogen Fire

First Name
Andy
Last Name
Piatt

A large, hydrogen-cooled generator is driven by steam turbines at a power station. During maintenance shutdowns, the hydrogen cooling loop in the generator is purged with carbon dioxide. After CO2 concentrations are measured with a densitometer to verify the complete removal of hydrogen, the generator is purged with air and the maintenance is performed.

Hydrogen Explosion at a Water Treatment Facility

First Name
Andy
Last Name
Piatt

A water treatment plant used an electrolytic process to generate sodium hypochlorite (NaOCl) from sodium chloride (NaCl). The strategy of using liquid sodium hypochlorite for disinfecting water instead of gaseous chlorine (CL2) is popular because the liquid is generally safer and falls under fewer OSHA and EPA standards. The further idea of generating the liquid sodium hypochlorite on an as-needed basis and in limited quantities also has certain obvious safety advantages.

Boiling Water Reactor Offgas System Mishap

First Name
Andy
Last Name
Piatt

An offgas system mishap involved two explosions occurring within an interval of about 3 ½ hours. The first offgas explosion was reportedly caused by a welding operation on an air line adjacent to a hydrogen sensor line containing off gas. The welding arc initiated a detonation within the offgas piping. The detonation was contained by the piping system but blew out the water seal at the base of the vent stack.The second hydrogen explosion in this incident occurred in the stack base area.

Pressure Reducing Clamp Removal Mishap

First Name
Andy
Last Name
Piatt

On a given day personnel were removing a blind hub that had been used to temporarily isolate a portion of a gaseous hydrogen system. As a result of a sudden release of 2,800 psig gaseous nitrogen, sand and debris kicked up from the concrete pad and caused minor injury to two technicians.

During the investigation, it was found that:

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