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Combustible Hydrogen Gas Vapors Ignited in a Battery Plant

Severity
Incident
Was Hydrogen Released?
Yes
Was There Ignition?
Yes
Incident Date
Incident Attributes
Describe the incident, including corrective steps taken and their result.

Summary

A fire occurred in a battery manufacturing plant that was about to cease operations for the night. The fire caused an estimated $2.4 million in property damage when an electrical source ignited combustible hydrogen vapors.

Background

The incident occurred in the forming room, where wet cell batteries were stored for charging on metal racks. The facility had a wet-pipe sprinkler system, but no automatic hydrogen detection equipment.

Incident Synopsis

At 11:52 pm, a security guard on patrol noticed a free burning fire in the forming room and notified the fire department. It took fire fighters almost three hours to bring the fire under control.

Although the facility was equipped with a wet-pipe sprinkler system, the forming room's branch had been disconnected 10 to 15 years before the incident. A press account said that acidic fumes from plant operations had led to repeated non-fire activations of the sprinklers in this room. The same account quoted a fire official as saying, "If the sprinklers had been working, we would have gone in there, swept some water away, changed a few sprinkler heads, and they'd be back in business."

The incident report doesn't indicate whether the owners ever considered the use of listed, corrosion-resistant sprinklers in this area.

Investigators determined that hydrogen gas, ignited by an electrical arc, was the cause of the fire. The hydrogen was generated by the electrical charging of the estimated 5,000 batteries on racks, and the electrical arc was initiated by the battery charging unit.

Lessons Learned

Although a functional fire protection system would have helped to extinguish the fire, a properly installed hydrogen detection system, coupled with a properly designed ventilation system, could have prevented the incident altogether.

Hydrogen rises twice as fast as helium, at a speed of 45 mph. Therefore, unless a roof or some other structure contains the rising gas, the laws of physics prevent hydrogen from lingering near its point of production. It is unclear weather the room's ventilation system wasn't functioning properly, or if it wasn't designed properly; but in either case, battery charging facilities need to consult experienced engineering firms on proper location and design of hydrogen detection and exhaust systems. On-site Standard Operating Procedures also need to mandate periodic functional/operational tests.

Adequate ventilation of battery charging facilities is addressed in the Lessons Learned Corner on this website.

Key:

  • = No Ignition
  • = Explosion
  • = Fire
Hydrogen Incident Summaries by Equipment and Primary Cause/Issue
Equipment / CauseEquipment Design or SelectionComponent FailureOperational ErrorInstallation or MaintenanceInadequate Gas or Flame DetectionEmergency Shutdown ResponseOther or Unknown
Hydrogen Gas Metal Cylinder or Regulator 3/31/2012
4/30/1995
2/6/2013
4/26/201012/31/1969  3/17/1999
11/1/2001
12/23/2003
Piping/Valves4/4/2002
2/2/2008
5/11/1999
4/20/1987
11/4/1997
12/31/1969
8/19/1986
7/27/1991
12/19/2004
2/6/2008
10/3/2008
4/5/2006
5/1/2007
9/19/2007
10/31/1980
2/7/20091/24/1999
2/24/2006
6/8/1998
12/31/1969
2/7/2009
9/1/1992
10/31/1980
10/3/2008 
Tubing/Fittings/Hose 9/23/1999
8/2/2004
8/6/2008
9/19/2007
1/1/19829/30/2004
10/7/2005
 10/7/2005 
Compressor 10/5/2009
6/10/2007
8/21/2008
1/15/2019
  10/5/20098/21/2008 
Liquid Hydrogen Tank or Delivery Truck4/27/198912/19/2004
1/19/2009
8/6/200412/31/1969 1/1/197412/17/2004
Pressure Relief Device7/25/2013
5/4/2012
1/15/2002
1/08/2007
12/31/1969    
Instrument1/15/20193/17/1999
12/31/1969
2/6/2013
  11/13/73  
Hydrogen Generation Equipment7/27/1999  10/23/2001   
Vehicle or Lift Truck 7/21/2011    2/8/2011
12/9/2010
Fuel Dispenser 8/2/2004
5/1/2007
6/11/2007
9/19/2007
 2/24/2006
1/22/2009
   
Fuel Cell Stack      5/3/2004
12/9/2010
2/8/2011
Hydrogen Cooled Generator   12/31/1969
2/7/2009
   
Other (floor drain, lab
anaerobic chamber,
heated glassware,
test chamber,
gaseous hydrogen
composite cylinder,
delivery truck)
 11/14/1994
7/21/2011
7/27/1999
6/28/2010
8/21/2008
12/31/1969
3/22/2018
  6/10/2019
  • = No Ignition
  • = Explosion
  • = Fire
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