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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Hydrogen Explosion in a Lh2 Storage Tank
The accident occurred in a testing site for space equipment. The high pressure combustion took place in a liquid hydrogen tank (H2) under a high pressure and in presence of 12 m (700 kg) of liquid H2. The test was stopped as the malfunction was detected by the sensors, without consequences. The cryogenic tank, with a nominal working pressure of 250 bar was connected to H2 gas and liquid oxygen storage tanks. Few months before, the test tank was emptied and purified (by injecting helium) as the H2 gas network was suspected of being polluted due to an intake of air from a compressor, one year before.The day of the accident, a test was performed: the liquid H2 tank was pressurized by a control device (up to 250 bar in 30 sec). When the pressure in the tank reached 160 bar, a noise indicating a pressure drop was observed and the detectors recorded a pressure fluctuation of 10 bar. The sudden and significant fluctuations of the measured parameters (temperature of wall, pressure, flow) brought to the termination of the test. The cause of the accident was the presence of combustion of frozen oxygen in an blind branch of the tanks drain pipe. Its presence was probably due to the partial unsuccessful purging by helium, which had not been able to purge the air contained in the blind pipe, because placed in the lower part of the tank. The trapped air had re-solidified when while refilling the tank with liquid H2. Several combustion spots were detected: in condensed phase between solid O2 and H2 gas, in less dense phase between H2 and O2 gas. The combustion was undoubtedly triggered by the friction of the pellets against the walls and the adiabatic compression of the H2/O2 gas mixture.
Event Date
December 4, 1991
Record Quality Indicator
Region / Country
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
Immediate cause was the presence of air/oxygen in a blind branch of a pipe, due to unsuccessful purging of the tank before refilling with LH2.
Facility Information
Application Type
Application
Specific Application Supply Chain Stage
Components Involved
liquid hydrogen cryogenic tank, testing hydrogen-oxygen mixture
Storage/Process Medium
Storage/Process Quantity
12
Actual Pressure
250
Location Type
Location description
Industrial Area
Operational Condition
Pre-event Summary
This event occurred in the area of propulsion system aerospace : rockets. It was a testing center and an isolated area with no admittance to the public.
Currency
Lessons Learned
Lessons Learned
Following an internal analysis and the improvement of processes, the system was put back in operation after 4 months of stop). Among the improvements introduced are:1. a new valve allowing for the regular purge of the dead branch of the pipe. 2. An operational process to avoid the accumulation of impurities which come with the delivered hydrogen. 3. Better monitoring/instrumentation
Event Nature
Emergency Action
After a risk analysis that led to doubts of the occurrence of an air pollution in the tank, an operation to purge the tank was carried out (Sub-event ID 53)
Emergency Evaluation
It was suspected to have a pollution of the tank (to be filled with hydrogen for tests) by air in October 1990 (more than a year before the combustion).
Ignition Source
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

Retour d'expérience issu de la mise en oeuvre d'un réservoir d'hydrogène liquide haute pression
Journée technique INERIS, du 7 octobre 2003

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