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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Fatal Hydrogen Explosion During Fertilizer Plant Tank Maintenance
The accident occurred during the maintenance of a sulfuric acid storage tank in an industry for the fertilizers production. The maintenance works consisted in cutting operations (to remove some plates fastened with bolts) by using oxyacetilenic flame on the storage tankOn the internal surface of a tank containing sulfuric acid a corrosion phenomenon associated with the accumulation of hydrogen occurred owing to poor maintenance. The hydrogen was then ignited by the oxyacetylenic flame. The explosion hurled the tank over a hangar, demolishing two other tanks (also containing sulfuric acid) and causing the escape of the product which invaded the basin of containment. The two men who were performing the cutting operation died. The released sulfuric acid evaporated from the basin originating a toxic cloud which dispersed without consequences for the population. The basin invaded by the sulfuric acid was emptied and neutralized with sodium carbonate in order to avoid that sulfuric acid could corrode the ammonia pipings inside the basin itself.
Event Date
October 10, 1985
Record Quality Indicator
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
The accident occurred because, on the internal surface of a tank containing sulfuric acid, a corrosion phenomenon associated with the accumulation of hydrogen occurred due to poor maintenance (caused by inadequate procedures). The hydrogen was then ignited by the oxyacetylenic flame used by two workers for cutting operations.
Facility Information
Application Type
Specific Application Supply Chain Stage
Components Involved
sulfuric acid storage tank, cutting tool, oxyacetilenic flame
Storage/Process Medium
Location Type
Location description
Industrial Area
Operational Condition
Pre-event Summary
The accident occurred during the maintenance of a sulfuric acid storage tank in an industry for the fertilizers production. The maintenance works consisted in cutting operations (to remove some plates fastened with bolts) by using oxyacetilenic flame on the storage tank.
Lessons Learned
Lessons Learned
No direct lesson learned from this event. However, this we page report general lesson learned and the evolution of this type of hazard prevention: http://www.sulfuric-acid.com/sulfuric-acid-on-the-web/Hydrogen-Safety.htm. This report goes well in details of single cases:http://www.sulfuric-acid.com/sulfuric-acid-on-the-web/Acid%20Engineering%20&%20Consulting%20Inc.%20-%20Leonard%20J.%20Friedman.pdf
Event Nature
Emergency Action
Unknown
Release Type
Release Substance
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

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