Recommended limits of heat flux for various exposures is provided in documents such as API Standard 521, the International Fire Code, the National Fire Protection Association and the Society of Fire Protection Engineers. Selection of a specific thermal radiation level is dependent upon a risk analysis. Some salient exposures are listed below.

• 1,577 W/m2 (500 Btu/hr ft2) is defined…

Yes, there are differences due to the differences in the fluid properties. We’re not sure what is meant by blowdown. If this means that should the gases be vented to a vent stack, possibly, but for certain these need to be vented to a safe location.

Relief device sizing for liquid hydrogen tanks follow recognized standards such as CGA S1.3. The sizing criteria include a worst-case scenario of an engulfing fire with loss of vacuum integrity.

LH2 tanks are unlikely to BLEVE due to the vacuum insulation outer jacket (usually carbon or stainless steel) preventing direct impingement of fire onto the main pressure vessel, as well as the…

Exhaust systems (sometimes referred to as ventilation systems) are used to exhaust hydrogen and air mixtures. Normally these are used to vent streams with less than flammable range hydrogen in air.

That is, hydrogen detectors trigger venting or the ventilation systems runs during all hydrogen operations. In these instances, low concentrations of hydrogen are expected, but deflagration is…

The deflagration pressure is dependent upon many variables.

However, some general concepts are:

1. Deflagration pressure is proportional to operating pressure
2. Deflagration pressure is inversely related to initial temperature
3. Deflagration pressure is based on concentration and H2/O2 ratio
4. In general, an internal deflagration is unlikely to exceed about a 10…

Liquid hydrogen will almost never accumulate in a vent system since vent systems are typically designed without insulation. The extremely cold liquid hydrogen temperature of -420 F.

Additionally, vent stacks on an LH2 tank are connected to the vapor phase of the tank. Only in a few rare instances will LH2 be entrained in the gas stream.

Accumulators are recommended at the bottom of…

1. Understand any reactions the hydrogen can add to what is being vented. For instance, O2/H2 vented in the same stack would not be a good idea.
2. Understand all the flow and operating parameters of the streams to ensure no back flow into the hydrogen system or vice versa.
3. Ensure the venting/flaring system can handle the hydrogen flow parameters.

Delayed ignition is a significant hazard for hydrogen releases, either intended or unintended. The primary concern is the overpressure and energy release created from a vapor cloud which could contain a significant quantity of hydrogen. The H2Tools Incidents database contains a number of examples of delayed ignition. 

Low-pressure vents at mostly low hydrogen purity are not as large safety risk as high-pressure pure hydrogen vents. These vents should still go to a vent stack, but it will probably be small in diameter and thus the tee vent at the top can be small.

If the purge requires high flow, if purging horizontally, the reaction forces of the flow exiting and the hydrogen cloud should be modeled…

A release is defined by the amount of hydrogen, the rate of hydrogen flow, vent location (indoors or outdoors), geometry in the area (confined or not), and pressure. 

A small or large release should be differentiated by the damage that can occur because of an ignition. This can be a fire, deflagration, or detonation.

Therefore, the relative size of the release will vary based…