A violent reaction occurred while hydrolyzing metal in water. The reactive metal treatment began with a review of the chemical inventory and setup of reaction vessels. The sodium metal was cut in shavings and added one at a time to the reaction vessel. After the second addition, an argon purge was added to disperse hydrogen gas faster. After approximately 10 pieces had been treated, the glass beaker shattered, releasing the contents of the reaction vessel (1 liter) inside the hood and causing the chemist's hand to receive superficial cuts. The process was being performed under a hood with all safety equipment in place. The employee was in personal protective equipment (PPE), but did receive two cuts on his hand through the glove. The treatment of reactive metals was being view more
A facility representative observed pipe-fitters enter a containment tent around a riser with a tool bag that contained a mixture of steel and copper/beryllium tools. The top flange was loosened using a copper/beryllium socket and a steel torque wrench. When questioned, the pipe-fitters correctly stated that this was allowable for initial loosening and tightening of these bolts. A copper/beryllium ratchet was used to accomplish the bolt removal. The bonded riser was shifted to allow access for the IH technician. The standard hydrogen monitoring system (SHMS) cabinet and local sample showed no hydrogen/flammable gas was present.
While the continuous vapor sample was being taken, the pipe-fitters proceeded to put together the copper/beryllium ratchet and socket with a 10" view more
A 30-milliliter (mL) vacuum bulb, equipped with a glass stopcock, containing one gram of pentacarbonyl manganese hydride exploded in a refrigerator. This caused the breakage of three other containers, releasing some contents into the refrigerator. The chemicals did not react. The refrigerator contained numerous reactive and flammable chemicals, mostly in glass containers.
The damaged containers were removed and relocated under a hood. The refrigerator was then examined for other breakage and inventoried. All breakage was cleaned up. The safety coordinator was notified and began an investigation.
The direct cause of the occurrence was the failure of a glass vacuum bulb, which either fractured due to some unforeseen chemical reaction forming hydrogen gas, or was unable to view more
The interior of a small high-temperature furnace, approximately 24 inches high by 18 inches wide, became contaminated with an unknown material later identified as magnesium. The furnace was disassembled to clean the unknown material from the interior surfaces, and while attempting to clean the bottom of the furnace, the technician tapped the upper lip of the furnace with a spatula and the magnesium flashed. The technician was stepping back from the furnace when the magnesium flashed. He received minor eye irritation and his eyebrows were singed.
Later that week the same technician was attempting to clean the interior surfaces of the top of the furnace and sprayed, as directed, the interior of the top with a water-based cleaning liquid which consisted of 91% water. He stepped view more
One afternoon, a hydrogen-monitoring system alarm sounded. The system isolated the building hydrogen gas distribution system from the source and purged the distribution piping with argon. Activities were terminated and personnel were immediately evacuated.
Prior to re-entry, the hydrogen system was walked down to ensure that it was in a safe state and that the remote indicator showed no hydrogen present in the facility. Normal operations were suspended until the cause of the alarm could be determined.
The cause of the alarm was not escaping hydrogen gas, but drift in one of the eight monitoring system sensors. The sensor was recalibrated and the monitoring system determined to be functioning properly. The gas distribution system was recharged with hydrogen and verified as view more
Facility management confirmed that a hydrogen gas cylinder did not comply with the limiting condition for operation (LCO) for flammable gas control systems in the lab's safety requirements. Earlier erroneous calculations had shown that a release of the entire contents of the cylinder into the hood could not reach the lower flammability limit (LFL).
The facility manager determined that the LCO was applicable and immediately entered the action statement in the safety system, which required immediate termination of normal operations in the affected wing of the building. Because normal operations had already been terminated in the wing for HVAC maintenance, further efforts to terminate normal operations were not necessary. The hydrogen cylinder was removed from the hood, thus view more
A small hydrogen fire occurred in a chemical process hood. A chemist was performing an experiment reacting manganese dioxide with hydrogen to produce manganese oxide and water. The chemist had left the process, which would take approximately one hour to complete, and was working in a nearby lab. While the chemist was gone, a second worker heard a pop, saw the hydrogen fire in the hood, and requested the activation of a fire alarm. A third employee in the area activated a manual fire alarm. The chemist, upon hearing the fire alarm, returned to the room, shut off the hydrogen fuel supply, and evacuated the facility. The hydrogen fire lasted for approximately one minute. The remaining small fire was extinguished about 10 minutes later with a HALON portable fire extinguisher by a view more
An unplanned shutdown of the hydrogen supply system occurred, affecting the hydrogen furnaces in the plant. The apparent cause was an inadvertent valve closing, which was contrary to the written procedure.
A preventative maintenance activity was being conducted on the hydrogen gas system. Shortly after starting that work, various hydrogen gas users notified the emergency response personnel that the hydrogen supply safety alarms sounded, indicating an interruption of the hydrogen gas supply. As a result, the hydrogen furnaces shut down. This shut down is an automated process which injects an inert gas (nitrogen or argon) to prevent the introduction of oxygen and its mixing with any hydrogen gas. All shut downs functioned as designed. As a precautionary measure, fire protection view more
A laboratory research technician entered a lab to begin preparing samples that were to ultimately be purged in an anaerobic chamber (glove box) located in that room. As the technician walked into the lab, she looked at the chamber to see if it was adequately inflated. This chamber is equipped with a gas concentration meter, capable of simultaneously displaying the oxygen and hydrogen concentrations of the chamber atmosphere. Under normal operating conditions, the atmosphere inside the chamber is comprised of 0% oxygen (as intended/desired for an anaerobic atmosphere), approximately 2-3% hydrogen, and with the remaining balance being nitrogen (approximately 98-97%). Under such normal operating conditions, the hydrogen concentration inside the chamber is less than the lower explosive view more
A health physics technician (HPT) discovered that a scaler in an analytical laboratory was out of P-10 gas (90%Ar and 10% CH4). The HPT went to the building where auxiliary gas cylinders are stored. He located a P-10 gas cylinder and turned to search for a hand-cart. There were no hand-carts present, and the technician had to get one from another room. When he returned to the cylinder storage area, he loaded the wrong cylinder. It contained hydrogen gas instead, however, the two cylinders were next to each other and they were basically identical. The empty cylinder was then replaced by the full one and the scaler was purged for several minutes before it was used. The alpha channel worked well, however, the beta channel did not respond. An instrument technician was contacted to identify view more