A person working in a hydrogen lab unknowingly closed the wrong hydrogen valve and proceeded to loosen a fitting in one of the hydrogen gas lines. The pressure in the 1/4"-diameter hydrogen line was approximately 110 psig. Hydrogen escaped from the loosened fitting and the pressure release resulted in the tubing completely detaching and falling to the floor. The person noted seeing a white stream around the hydrogen jet leak. The person noted a color change and noise change as the leak ignited (this happened in a matter seconds and he did not have a chance to react). The person left the lab and pushed the emergency stop button. Someone else pulled the fire alarm. Both of these actions were designed to close the main hydrogen solenoid (shutoff) valve. The local emergency response view more
An explosion occurred in a Microbiological Anaerobic Chamber of approximately 2 m3 capacity that contained an explosive mixture of hydrogen and air. A fire followed the explosion, but was rapidly extinguished by staff using fire extinguishers prior to the arrival of fire service personnel. The pressure wave from the explosion blew windows out of the laboratory, with glass hitting a passerby on a path outside and glass shards landing up to 30 m away. Ceiling panels were dislodged in the laboratory and adjacent rooms, and a worker using the apparatus at the time was taken to the hospital by ambulance for burn treatment. The worker subsequently fully recovered. Another worker in the lab at the time required medical observation, but was otherwise unharmed.
Mixtures of inert gases view more
An incident involved an explosion of an oven that was heating decaborane for vaporization. In this incident, the heater controller was defective so the heating element was disconnected from the controller and plugged directly into a wall outlet. This situation allowed the oven to reach temperatures in excess of 400 °C within 20 minutes. While the temperature increased, the decaborane continued to expand, causing a significant pressure build-up within the oven. The pressure increase eventually caused the oven's viewing window to burst. A burst of burning hydrogen was emitted from the window and burned the face of a researcher who was hospitalized for approximately three weeks.
An apprentice mechanic lacerated his right forearm while quickly sliding out from under a hydrogen prototype bus when the bus slipped off a hydraulic jack. The apprentice and another mechanic had raised the bus about 1 foot from the ground to position it on jack stands when the hydraulic jack tipped over. The apprentice went to the site medical facility, where he needed five stitches to close the wound in his forearm.
The mechanics were raising the rear of a hydrogen prototype bus, like the one in the figure below, and placing it on jack stands. After chocking the wheels, they used bottle jacks on each side of the rear axle to raise the bus high enough to place a 20-ton hydraulic jack under the differential. With the bus resting on a pair of small jack stands, they raised the view more
A researcher was working with hydrogen storage materials in a laboratory. Several other researchers were working in adjacent laboratories.
The researcher had prepared a sample of aluminum deuteride, AlD3, by reacting lithium aluminum deuteride and aluminum chloride in diethyl ether. The actual composition/phase of the material synthesized was unknown, but the researcher had attempted to produce the gamma phase of aluminum deuteride. The synthesis steps used to produce the material were complete and the researcher attempted to seal the material in a glass ampoule for offsite shipment and analysis. The sample size was approximately 1 gram.
The ampoule with the sample had previously been placed under vacuum and had been isolated from the atmosphere. The process for sealing view more