During restart of an ammonia production plant, syngas (50% hydrogen mixed with methane, ammonia, and nitrogen) leaking from a flange directly downstream of the synthesis reactor ignited. The plant had been shut down for about 90 minutes due to a technical problem. Alerted by the plant fire alarm, the operator activated the emergency shutdown, which isolated and depressurized the synthesis loop. Steam was sprayed onto the leak site to dampen the fire, which was brought under control 55 minutes later. Property damages included pipe insulation, the reactor's protective shutters, concrete fireproofing of the reactor structure, and instrumentation cables within 3 meters of the leak site. The flames did not affect the synthesis reactor itself, which was protected by a deflector. The view more