A hydrogenation experiment was being performed under 60 atm hydrogen, inside a high-pressure reactor cell. The experiment was conducted inside a fume hood and left overnight. The hood caught fire during the night, resulting in fire damage to the fixture, hood, and exhaust duct, as well as water damage to much of the building. Based on the local fire department investigation, the fire started from faulty electrical wiring that was used to provide power for reactor cell heating. The electrical fire ignited solvent that was in a dispensing bottle inside the hood, which subsequently overheated the reactor cell, rupturing the seals. The rupture released hydrogen from the cell and attached supply tank, further fueling the fire. Nobody was injured in the incident, and damages were limited. It view more
A rupture disc blew on a 20,000-gallon liquid hydrogen tank, causing the vent stack to exhaust cold gaseous hydrogen. Emergency responders were called to the scene. To stabilize the tank, the remaining hydrogen was removed from the tank except for a small volume in the heel of the tank that could not be removed manually. The tank vacuum was lost. Firemen sprayed the tank with water and directed a stream onto the fire exiting the vent stack. The water was channeled directly into the open vent stack, and the exiting residual hydrogen gas (between -423 F and -402 F) caused the water in the vent stack to freeze. The water freezing caused the vent stack to be sealed off, disabling the only exit for the cold hydrogen gas. After a time, the residual hydrogen gas in the tank warmed up, causing view more
Hydrogen was released near the ground when the vent line from a 13,000-gallon liquid hydrogen storage vessel suffered damage from unusually high winds. The toppled vent line did not shear or tear, but sustained a kink that restricted hydrogen flow and created a back pressure on the vessel relief system.
Repair efforts were hampered by the potential for cold hydrogen gas, a flammability hazard, in the work area. Shut off or redirection of the hydrogen was not possible, and variable breezes made set up of safe zones uncertain. A protocol had not been prepared for this scenario.
An explosion occurred within the hydrogen processing system of a chemical plant that produces sodium chlorate for bleaching pulp and paper. The chemical process utilizes electrolytic cells and is pH-dependent. Hydrogen is produced as a byproduct and is utilized as a fuel.
At the time of the incident, the plant was at an abnormal operating level of 25% capacity. A non-routine maintenance operation to repair high-pH liquid piping was in progress. To assist, operations personnel rerouted the high-pH liquid stream to the plant sump. However, in doing this, the liquid eventually made its way back into the electrolytic process by design. Ultimately this created the root cause of the explosive condition in that the pH of the electrolytic process increased faster than the computer- view more
A pressure relief device (PRD) valve failed on a high-pressure storage tube at a hydrogen fueling station, causing the release of approximately 300 kilograms of hydrogen gas. The gas ignited at the exit of the vent pipe and burned for 2-1/2 hours until technicians were permitted by the local fire department to enter the station and stop the flow of gas. During this incident the fire department evacuated nearby businesses and an elementary school, closed adjacent streets, and ordered a high school to shelter in place.
There were no injuries and very little property damage. The corrugated roof on an adjacent canopy over a fueling dispenser was slightly singed by the escaping hydrogen flame, causing less than $300 in damage.
The station's operating systems worked as view more
Severe vibrations caused by broken low-pressure turbine blades damaged the main turbine generator at a nuclear power plant. These vibrations also caused multiple hydrogen leaks at equipment connections to the generator, resulting in hydrogen flames outside of the generator casing that caused minimal damage to the facility. Hydrogen is used to internally cool the plant's electric generators. Water from the fire suppression system and oil released from the turbine lube oil system during the event were contained within the plant, resulting in no impact to the environment. The plant's nuclear systems were unaffected by the event.