A trained operator was blending water, sand, anhydrite, lime, cement, pulverized fly ash, and powdered aluminum in a mixing chamber to produce material for making concrete building blocks. In the blending process, sand and water are mixed to form a slurry, and then the powders are dispensed automatically into the mix by a computer-controlled system. Finally, a slurry of glycol-coated aluminum powder is added in the last few seconds before the mix is discharged into a car, and then molds are filled from the car. Adding aluminum to the mixture results in a small amount of hydrogen gas evolution, which disperses from the car into the surrounding ventilated area and out through roof vents. In addition to being an ingredient of the mix, water also helps to keep the mixture cool.
A hydrogen leak at the flange of a 6-inch synthesis turbocharger valve in an ammonia production plant ignited and exploded. Hydrogen detectors and the fire alarm alerted the control room, which immediately shut down the plant, and the fire was then extinguished rapidly. There were no injuries caused by the accident, since the operator heard a wheezing sound and was able to run away just before the explosion occurred. The leaking gas was composed of 70% hydrogen at a flow rate of 15,000 cubic meters per hour. Property damages in the turbocharger included electrical cabling, melted siding, and heavily damaged pipes. The ammonia plant was shut down for more than a month.Five days before the incident, a problem with the CO2 absorber column led operators to open the vent downstream of the view more
Operators in a powdered metals production facility heard a hissing noise near one of the plant furnaces and determined that it was a gas leak in the trench below the furnaces. The trench carried hydrogen, nitrogen, and cooling water runoff pipes as well as a vent pipe for the furnaces.
Maintenance personnel presumed that the leak was nonflammable nitrogen because there had recently been a nitrogen piping leak elsewhere in the plant. Using the plant's overhead crane, they removed some of the heavy trench covers. They determined that the leak was in an area that the crane could not reach, so they brought in a forklift with a chain to remove the trench covers in that area.
Eyewitnesses stated that as the first trench cover was wrenched from its position by the forklift view more
A researcher was unplugging an electrical cord when 1/8-inch copper tubing supplying nitrogen to a gas chromatograph came in contact with the energized electrical plug, causing an electrical arc. This caused a hole in the copper tubing. A nearby hydrogen line was unaffected.
The bottled gas supply was shut off. Craftsmen were brought in to reinstall the copper tubing, at a safe distance from the electrical outlet.
In early afternoon, a northbound tractor-semitrailer with horizontally mounted tubes filled with compressed hydrogen at approximately 2400 psi (166 bar) was struck by a northbound pickup truck that veered into the semitrailer's right rear axle. According to witnesses, the tractor-semitrailer then went out of control and left the roadway, coming to rest approximately 300 feet (91 meters) from the point of impact. As a result of rotational torque and impact, the end of one tube was sheared off at the bulkhead and left the tube bundle. During the process, some of the tubes, valves, piping, and fittings at the rear of the semitrailer were damaged and released hydrogen. The hydrogen ignited and burned the rear of the semitrailer. In the meantime, the pickup truck had also run off the view more
A hydrogen leak occurred at a plant's hydrogen fill station when a vendor's hydrogen fill truck trailer pulled away after filling and caught an improperly stored hydrogen fill line. The driver of the hydrogen truck trailer did not properly stow the hydrogen fill line after filling and failed to verify that the hydrogen fill line was clear of the trailer prior to departure. As the driver pulled away from the fill station, the hydrogen fill line caught on the trailer and subsequently pulled on the hydrogen fill station's ground storage tubes distribution manifold. The force of this pull bent the plant's hydrogen distribution manifold and hydrogen began leaking from a threaded connection and from the hydrogen fill line. The truck trailer driver reported hearing a view more
A hydrogen leak occurred from a 1-inch gate valve on a makeup gas line in an oil refinery gas oil hydrotreater unit. When the leak was discovered, the gas oil hydrotreater unit shutdown procedures were immediately implemented and emergency response was requested. The refinery response team along with county response teams responded, and after approximately 1/2 hour, the gas oil hydrotreater unit was fully shut down. Shutdown consisted of sufficiently depressurizing the unit and adding nitrogen to allow safe closing of the leaking 1-inch gate valve and installation of the associated missing bull plug.
During this event, the 1-inch gate valve was found to be open roughly 10% with no bull plug in the valve, allowing the hydrogen to leak to the atmosphere. In addition, a 1-inch bull view more
A small research sample of approximately 5 grams of aluminum hydride (alane) doped with 2-3 mol % TiCl3 contained within a glass ampoule ruptured after transit while stored in an office cabinet. The rupture was attributed to over-pressurization caused by hydrogen gas buildup within the sample over a four-month period. The glass ampoule, contained within a 0.2-inch thick cardboard shipping tube, was not a pressure-rated container. The rupture resulted in glass chards penetrating the protective cardboard shipping tube. The aluminum hydride, a fine powder, was released from the shipping tube during the pressure release. The fine aluminum powder leaked from the cabinet and set off a local smoke alarm that brought emergency responders to the scene. No personnel were present in the area when view more
A hydrogen fire occurred in an early morning accident involving a hydrogen tube trailer and multiple vehicles on a rural highway. The cause of the collision is unknown, however, it appears to be unrelated to hydrogen (i.e., it was likely human driving errors). The hydrogen tubes contained compressed hydrogen gas at a pressure of 15 bar (218 psi). The accident caused a leak in the hydrogen plumbing system and deformed one of the hydrogen tubes, resulting in a 10-centimeter (4-inch) longitudinal crack from which hydrogen began to leak (see Figures 1 and 2). Fire from the conventional vehicles trapped under the hydrogen tube trailer during the accident ignited combustible components on the tube trailer (tires and fuel/oil), and subsequently the leaking hydrogen. Emergency crews arrived view more
During a refueling event, the operator activated the fueling lever in the wrong sequence. The vehicle filled to proper pressure, but filled faster than normal. Under different circumstances, this could have resulted in overheating of the receiving fuel tank.