Hydrogen Explosion at a Water Treatment Facility

First Name
Andy
Last Name
Piatt

A water treatment plant used an electrolytic process to generate sodium hypochlorite (NaOCl) from sodium chloride (NaCl). The strategy of using liquid sodium hypochlorite for disinfecting water instead of gaseous chlorine (CL2) is popular because the liquid is generally safer and falls under fewer OSHA and EPA standards. The further idea of generating the liquid sodium hypochlorite on an as-needed basis and in limited quantities also has certain obvious safety advantages.

Boiling Water Reactor Offgas System Mishap

First Name
Andy
Last Name
Piatt

An offgas system mishap involved two explosions occurring within an interval of about 3 ½ hours. The first offgas explosion was reportedly caused by a welding operation on an air line adjacent to a hydrogen sensor line containing off gas. The welding arc initiated a detonation within the offgas piping. The detonation was contained by the piping system but blew out the water seal at the base of the vent stack.The second hydrogen explosion in this incident occurred in the stack base area.

Nickel Cadmium Battery Explosion

First Name
Andy
Last Name
Piatt

Incident Synopsis
During routine facility maintenance of an automatic battery charging system, 6 of 27 nickel cadmium batteries being reinstalled exploded.

Cause
Inadequate work procedures in that a probable cause was ignition of accumulated hydrogen gas by a spark generated during the replacement work, and inadequate ventilation of the battery area; a second probable cause was stopped up vent caps, resulting from contaminated electrolyte, which permitted hydrogen pressure build up to an explosive force in the 6 batteries.

 

Potential Catalyst Fire Hazard with Oxygen Generator Filter Change-out Maintenance

First Name
Andy
Last Name
Piatt

Within the International Space Station (ISS) oxygen generator, an increase in differential pressure across a pump supplying return water to a PEM electrolyzer fuel cell stack had persisted over a 4-month period and was approaching the shut-off limit for the system. This decrease in performance was suspected to be caused by water-borne catalyst fines containing platinum black and Teflon®* binder materials, shed by the fuel cell stack, and accumulated within the pump's inlet filter. Maintenance in the field was required.

Gas Chromatograph Piping Leak Explodes in Instrument Room

First Name
Andy
Last Name
Piatt

An explosion occurred at a chemical plant in an analysis room containing various analyzer instruments, including a gas chromatograph supplied with hydrogen. A contract operator was performing work to install a new vent line to a benzene analyzer that was part of a group of CO2 analyzers, but separate and unrelated to the gas chromatograph. During the process of this work, a plant supervisor accompanying the contract operator doing the work had an indication of flammable gas present on a portable detector.

Hydrogen Explosion in University Biochemistry Laboratory

First Name
Andy
Last Name
Piatt

A hydrogen explosion occurred in a university biochemistry laboratory. Four persons were taken to the hospital for injuries. Three of these were treated and released shortly thereafter; the fourth was kept overnight and released the following evening. All of the exterior windows in the laboratory were blown out and there was significant damage within the laboratory. One sprinkler was activated that controlled a fire associated with a compressed hydrogen gas cylinder.

Hydrogen Fire in a Storage Vessel

First Name
Andy
Last Name
Piatt

In the fall of 2007, the operations team began a procedure (a written procedure was being followed) to sample the liquid hydrogen (LH2) storage vessels ("tanks"), and associated transfer system. This procedure was being performed to determine the conditions within the system, and if necessary, to purge the system of any excess gaseous hydrogen (GH2) in preparation for reactivation of the system. The system had not been used since 2003.

Hydrogen Explosion in a Styrene Plant

First Name
Andy
Last Name
Piatt

A hydrogen explosion and fire occurred in the benzene unit of a styrene plant in a large petrochemical complex. The unit was being restarted following a scheduled maintenance shutdown. The explosion followed the release of about 30 kilograms of 700-psig hydrogen gas from a burst flange into a compressor shed. Two men were killed and two others were injured. If it had not been a holiday, the death toll and injuries would probably have been much worse.

Hydrogen Gas Explosion in Municipal Refuse Incineration Facility

First Name
Andy
Last Name
Piatt

An explosion occurred in a 90-ton-per-day incinerator at a municipal refuse incineration facility. Three workers were seriously burned by high-temperature gas that spouted from the inspection door, and one of them died 10 days later. The accident happened during inspection and repair of the furnace ash chute damper. The workers injected water to remove some blockage, and the water reacted with incinerated aluminum ash to form hydrogen, which caused the explosion.

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