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Fire When Refilling a Cylinder at a Hydrogen Storage Facility (1036)

While filling a 9 litre gas cylinder with pressurised hydrogen in the hydrogen storage area, a blast occurred which destroyed the low pressure gauge, followed by a jet fire which damaged the surface of the cylinder.The cylinder to be filled, including pressure gauge and control system, had been provided by a third party. Its nominal pressure was 35 MPa, however the maximal pressure of this filling would have been much lower, less than 20 MPa, corresponding to the maximal pressure of the bulk storage available.

Prd Failing to Open (1035)

A cryogenic hydrogen laboratory had a power outage. The cryogenic hydrogen storage was no longer being cooled, therefore temperatures and pressures within the storage system started rising. There were several relief devices on the system, one with a set point of 150 psi (approximately 1 MPa) and a second at a set point of 165 psi (1.1 MPa). The system was monitored by site personnel so that when the hydrogen pressure increased to 120 psi (approximately 0.5 MPa), a manual vent was opened. However, the manual vent rate was not able to control the rising pressure.

Release of a Pressure Release Valve (1034)

A hydrogen safety sensor went into alarm at a hydrogen demonstration facility. The early morning temperature was near freezing and there was a trace of precipitation on exposed surfaces. Upon further inspection following the sensor alarm, a 3,500 psig (approximately 24 MPa) stationary storage vent was found to be releasing hydrogen through the PRD vent stack (PRD = Pressure Relief Device). The alarming sensor was at an adjacent building but responded to hydrogen 20 yards (18 m) downwind from the vent location. The vent release location is 10 feet (3 m) above ground level.

Explosion of an Autoclave in a Laboratory (1033)

A researcher was conducting an experiment that involved sawdust being heated at pressure using hydrogen gas in an laboratory-scale autoclave.The gas leaked from the autoclave during the experiment and ignited, causing injuries to the scientist (cuts, bruises and facial burns).The explosion caused extensive damage to the building, propelling debris more than 20 metres into a garden area.

Hydrogen Release from a Public Transport Bus (1029)

The accident occurred at a production, distribution and storage station for hydrogen city busses. After filling the hydrogen cylinders of a bus, the hydrogen detection system of the bus triggered an alarm. The site technician pushed the emergency button and the station was put in safety mode. The technician in charge of filling disconnected the hydrogen hose that connects the station to the bus. The maintenance manager of the bus manufacturer was alerted and arrived 20 minutes later and evacuated the personnel. They closed the valves of the on-board storage system.

Explosion of a Hydrogen Pipeline (1027)

During agricultural drainage work carried out by a farmer, an explosion occurred on a hydrogen pipeline located in a field. Flames several meters high were visible and two houses were evacuated. A safety perimeter was set up. The pipeline operator applied procedures to ensure the safety of the local residents and the pipeline.The damaged pipe was listed by the operator. The farmer did not declare the work site and no verification was done before starting the work.[ARIA event 57406]

Implosion/Explosion on a Furnace Copper Metallurgy Company (1026)

An implosion/explosion occurred on a furnace in a company of copper metallurgy. The incident occurred at the end of the production cycle, when the furnace bell is lifted at the end of the cooling process. The operator in charge of the lifting was thrown away and slightly burned in the face. The victim was evacuated and the emergency services were alerted. The building structures (windows, doors, roof) experienced serious damage. The power supply was switched off.

Hydrogen Formation and Explosion in Zinc-Coated Sprinkler System (1021)

[NOTE: the attribution to hydrogen formation as cause of the explosion is 'probable 'but not fully demonstrated].Two explosions in two different sprinkler systems occurred, wit the same assumed cause.The first occurred at the premises of a company, where a service engineer was injured, even though the explosion actually moved out into the open air. The second occurred in the department store, where an installation contractor was burned because an explosion occurred in a large pressure storage tank in a small room with the result that the explosion was particularly powerful.

Accidental Formation of Flammable Gas from Chemical Waste on a Ship (1020)

During the shipments of incinerator bottom ash, flammable gasses including hydrogen generated and caused two explosions. The first explosion was in the forecastle store and the second in the cargo hold.The vessel was loaded with a cargo of 2333 tonnes of unprocessed incinerator bottom ash. The chief engineer, who was inside the forecastle store at the time, suffered second degree burns and was airlifted to a nearby hospital.
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