Explosion Due to a Release from a Hydrogen Storage Tank
on a Sunday morning, in a ceramic factory, a leak on a 100 m tank containing 370 kg of hydrogen caused an explosion. The generated pressure wave causes significant damage to exterior buildings (broken windows, fire starts); a fragment of the tank was found several hundred meters from the place of the explosion. The human toll shows 23 people from the public who were slightly injured. A fire broke out soon after on the site and threatened storage of acetylene and hydrogen fluoride. A safety perimeter of 500 m is set up, road and rail traffic are stopped, the population evacuated.The tank at the origin of the accident had been put into service in December 1982, after having been modified to notably increase its storage capacity. Its first regulatory check after 5 years of use had revealed nothing abnormal, the second was to take place a few months after the accident. Operating at a maximum operating pressure of 44.1 bar, the storage was replenished as soon as its pressure fell below 15 bar (several times a week). The last loading by an external company had been carried out less than 2 hours before the explosion.Fatigue corrosion was the source of the leak that caused the explosion. The modification work carried out on the tank and in particular the removal of the roof along the weld had caused a deformation of the tank (oval instead of circular section) and induced tension in the material. Frequent filling of the repository only accelerated the weakening process of the tank.
Event Date
October 5, 1991
Record Quality Indicator
Region / Country
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Causes
Cause Comments
Immediate cause was the hydrogen release caused by fatigue corrosion of the tank material (valve, welded area).On the root cause can only be speculated: the modification work had induced a change of shape of the tank, this could be related to a operation cause or even a design cause.
Facility Information
Application Type
Application
Specific Application Supply Chain Stage
Components Involved
hydrogen storage tank
Storage/Process Medium
Storage/Process Quantity
370
Location Type
Location description
Industrial Area
Pre-event Summary
The tank at the origin of the accident had been put into service in December 1982, after having been modified to notably increase its storage capacity. Its first regulatory check after 5 years of use had revealed nothing abnormal, the second was to take place a few months after the accident. Operating at a maximum operating pressure of 44.1 bar, the storage was replenished as soon as its pressure fell below 15 bar (several times a week). The last loading by an external company had been carried out less than 2 hours before the explosion.
Number of Fatalities
3
Currency
Event Nature
Emergency Action
The police delimited an area (500 metres large) around the plant. The rail traffic was stopped and the road traffic deviated.
Release Type
Release Substance
Hydrogen Release Concentration (%)
100.00
Release Amount (kg)
370.00
Release Pressure (bar)
44.00
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Flame Type
Source Category
References
References
eMARS database
https://emars.jrc.ec.europa.eu/en/eMARS/accident/view/55bcb83b-282f-439…
(accessed July 2020)
G. Reichardt,
Wasserstoffexplosion im Werk der Firma Haereus Quarzglas GmbH, Hanau,
VGB Kaftwerkstechnik73 (1993) heft 8
ARIA event No. 2903