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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Explosion at an Electrolyzer at a Refueling Station
This incident occurred at the electrolyzer of a refuelling station. An employee of the electrolyzers manufacturer was on-site to conduct a reset of the plant power breaker system and to restart gas generation. Whilst putting the system into generation, a loud bang was heard. By reviewing the station CCTV evidence, a cloud of water vapour was seen being emitted from the oxygen vent line of the electrolyzer container. The gas generation system was safely shut down, and an investigation was started to understand the cause and potential impacts. The on-site investigation revealed no visible damage to electrolyzer equipment, including the water purification system, the oxygen exhaust pipe. On the contrary, damage was observed in the stack: the stack initially developed a crack in the first foil on the bottom end-plate (cause unknown). It is likely that this was causing a leak and an increase in the pressure drop. But very probably this drop was not big enough to be detected during the pressure drop test. The stack could still generate at pressure as the rate of generation would be greater than the leak rate. From analysis of the data, set-points designed to detect this type of failure mode where shown to have been adjusted from those initially set. Therefore the plant did not automatically alarm at the appropriate time to stop all operations.An important part of the study was to understand if the cloud was water vapour or smoke. Since no evidence of a flame and no heat damage to pipework were found, it can be concluded that the cloud was water vapour and not a result of a fire. The water vapour was released due to combining small amounts of hydrogen and oxygen gas within the stack system.
Event Date
April 30, 2020
Record Quality Indicator
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
According to the investigation, the immediate cause of the bang was probably a recombination of hydrogen and oxygen in the oxygen exhaust pipe. The report calls it a recombination, because no heat damage could be detected. But in general, the recombination of oxygen and hydrogen occurring with a bang, is called an explosion. The present of hydrogen was caused by a damage of the sealing in the electrolyzer's stack.
Facility Information
Application Type
Application
Specific Application Supply Chain Stage
Components Involved
stack
Storage/Process Medium
Location Type
Location description
Industrial Area Near A Motorway
Operational Condition
Pre-event Summary
The electrolyzer was being restarted after maintenance.
Consequences
Number of Injured Persons
1
Lessons Learned
Lessons Learned
The electrolyzer manufacturer have set up a dedicated team to review and report on the stacks optimal operating conditions to avoid stack damage leading to cross over situations. It also reviewed all active plants in respect to the management of the alarms, their set-points, escalations routes and improved data analysis function within the control room. An important improvement has been an earlier escalations of the alarms to the technology experts.
Event Nature
Emergency Action
No emergency known
Release Type
Release Substance
Hydrogen Release Concentration (%)
100.00
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

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