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Explosion and Fire in a Chemical Plant Producing Aromatic Hydrocarbon (959)

A gaseous mixture of hydrogen (H2), methane (CH4) and ethane (CH3-CH3) at 54 bar was cooled in a heat exchanger upstream of a hydrogen purification system. The accident started with a double explosion followed by a fire.The heater used to regenerate the adsorbent beds of the purification unit had been repaired a few hours earlier, but the automatic heating mode had not been activated upon restart. Therefore, two regeneration cycles had been carried out cold, causing an overload of the adsorber and the fouling of the heat exchanger.

Hydrogen Fire in a Refinery (958)

A hydrogen leak occurred on the hydrogen line of a hydro-desulfurization unit, followed by ignition . The failure was located on a supply manifold of the unit at a support beam. The unit was shut down.The accident was caused by external corrosion which had developed at a support point, under the pipe insulation. A regular thinning of the piping was observed over a length of 450 mm on the lower semi-circumference. The maximum thickness loss was 6.5 mm. The mechanical analysis concluded that the operating pressure was sufficient to cause this initial failure in the weakened area.

Hydrogen Release from a Liquid Hydrogen Truck (956)

The truck was carrying 25 m3 of liquid hydrogen and was parked in the parking lot of a road restaurant. The hydrogen escaped through the safety devices of the tank and then dispersed (the weather was wet and there is fog). Technicians from the charter company degassed the tank until the leak stopped, then escorted the truck to a technical centre. A crack in the inner tank causing a pressure build-up could be the cause of the accident.

Hydrogen Bottles Truck Crash and Hydrogen Release (954)

Since the release could not be stopped by intervening at the leaking point, the fire brigade decided to vent the whole content of the pallet (246 m3) by gradually opening the valves and by keeping the rack cool. The rack of the bottles was empty after four hours and the rescue operation ends at noon after the cylinder rack has been checked by an expert from the gas supply company. The residents returned to their homes and the plant's activity restarted one hour later.

Hydrogen Leak at a Refinery (952)

The release occurred on a pipeline inside a steam cracking unit located between two hydrogenation units. The gaseous mixture transported through this line (2" diameter, 30 bar, 40C) was composed of 95% hydrogen, 4% methane and 1% nitrogen. The line was located in a rack within the cold sector, at a height of 6 m. The personnel shut down the steam cracker and isolated the sector and the units cuts were sent to the flare system.
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