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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Hydrogen Leak at a Refinery
The release occurred on a pipeline inside a steam cracking unit located between two hydrogenation units. The gaseous mixture transported through this line (2" diameter, 30 bar, 40C) was composed of 95% hydrogen, 4% methane and 1% nitrogen. The line was located in a rack within the cold sector, at a height of 6 m. The personnel shut down the steam cracker and isolated the sector and the units cuts were sent to the flare system. The leak was successfully sealed at noon, and the steam cracker remained down for a full 24 hours.Runoff due to water vapour condensation was observed on a cold pipe located above the perforated piping assembly. This drop-by-drop action had weakened the pipeline, causing corrosion and thinning of the upper surface. The perforation had resulted from a pressure shock during operation. The Classified Facilities inspection authorities noted that the pipeline had not been protected against corrosion by a coat of paint. This pipe section, had been monitored by an accredited inspection body focusing on individual problem areas, repainted in 1990 and then verified in both 2000 and 2007. However, during this last inspection, it had been commented that the particular section was inaccessible due to the expansion layer formed by corrosion/erosion and therefore could not be controlled. The 2007 investigations did not allow for measuring the magnitude of corrosion, and no specific guideline was issued for the restoration of this section (painting work at the very least). The inspectors also noticed runoff on the pipe racks through this zone, along with a major degradation of pipe paint, which in some cases had totally disappeared.
Event Date
February 15, 2010
Record Quality Indicator
Region / Country
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
Immediate cause of the leak was the weakening of the pipe due to external corrosion by water drop, followed by a mechanical shock during operation.According to the ARIA report (see references) the root cause was the inadequate inspection and consequent failure of damage detection and repair.
Facility Information
Application Type
Specific Application Supply Chain Stage
Components Involved
pipeline, steam cracker
Storage/Process Medium
Actual Pressure
30
Design Pressure
30
Location Type
Location description
Industrial Area
Currency
Lessons Learned
Lessons Learned
The ARIA report (see references) does not mention corrective actions, but it appears clear that the inspection methodology must improve, to avoid recurrence of similar accidents.
Event Nature
Emergency Action
The personnel shut down the steam cracker before repairing the pipeline; isolated the sector and the steam crackers sent to the flare system. The leak was successfully sealed at after 10 hours, and the steam cracker remained down for a full 24 hours.
Release Type
Hydrogen Release Concentration (%)
95.00
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

Event description in the French database ARIA
https://www.aria.developpement-durable.gouv.fr/accident/38140/
(accessed October 2020)

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