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This data is from the European Hydrogen Incidents and Accidents database HIAD 2.1, European Commission, Joint Research Centre.

Gas Release from the Hydrocracking Unit of a Refinery
The gas leak containing hydrogen (H2) and hydrogen sulfide (H2S) occurred at the upper isolation valve located at a high-pressure separator (300 bar) of an oil production unit in a refinery. DESCRIPTION of the PROCESSAfter hydrocracking under high pressure and temperature, the oil viscosity is adjusted by means of reaction with a catalyst, hydrogen and a load of distillates. At the outlet, the high-pressure separator enables gases to be separated from liquids, with the latter channelled towards the low-pressure section by opening a valve. The uncondensed gases in the high-pressure separator are mainly composed of H2 and H2S.The SEQUENCETo control this valve, two measurements of the level of the mixture are necessary to prevent the entry of gas into the low-pressure section. A maintenance intervention was scheduled to replace one of the faulty level sensor. During the operation, the piece used to operate the valve broke without causing a leak. Thirty minutes later, the upper part of the valve was ejected under the effect of pressure, causing the release of about 25 litres of hydrogen.The CONSEQUENCEThe leak occurred 4 m aboveground and had no direct impact on staff. After depressurisation by gas flare, the equipment was purged by inert gas (nitrogen), which caused several successive sudden rises in pressure within the gas flare network along with the valve release. The amount of gas released by the gas flare during the day was estimated at 13 tonnes.
Event Date
July 13, 2007
Record Quality Indicator
Region / Country
Event Initiating System
Classification of the Physical Effects
Nature of the Consequences
Cause Comments
Immediate cause of he leak was the failure of a valve in the high-pressure part of a gas separator.Root cause was design defect of that type of valve.
Facility Information
Application Type
Application
Specific Application Supply Chain Stage
Components Involved
high-pressure separator (300 bar) of an oil production unit
Storage/Process Medium
Actual Pressure
300
Design Pressure
300
Location Type
Location description
Industrial Area
Pre-event Summary
Two level measurements were necessary to prevent the entry of gas into the low-pressure section. A maintenance intervention was scheduled to replace one of the faulty level sensors located on a standpipe of the high-pressure separator. During the operation, the square of the upper quarter-turn valve broke without causing a leak. Thirty minutes later, the upper part of the valve was ejected under the effect of pressure, causing the release of about 25 liters of hydrogen.
Lessons Learned
Lessons Learned
Unknown
Event Nature
Emergency Action
After depressurisation by gas flare, the equipment was purged with nitrogen, which caused several successive and sudden rises in pressure within the gas flare network along with the valve release.
Release Type
Release Amount (kg)
13000.00
Detonation
No
Deflagration
No
High Pressure Explosion
No
High Voltage Explosion
No
Source Category
References
References

ARIA data base
event no. 33332

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