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Hazards Analysis, Properties

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Hazards Analysis, Properties

Flammable hydrogen releases can result in deflagration and transition to a detonation. Whether the
deflagration transitions to a detonation depends on numerous parameters such as cloud size, hydrogen
concentration, confinement, and congestion. Releases into confined or congested areas are more
susceptible to generating significant deflagration over-pressures and more likely to…

There are numerous models that can be used to assess the consequence and risk of leaks and releases.
One such model is HYRAM which is publicly available from Sandia and the US DOE.

Emergency response procedures must be developed for each system based on its design. The
procedures generally include steps to clear personnel from the immediate area, isolate the hydrogen,
shut down the equipment, contact local responders, and protect surrounding equipment/structures until
the hazard is mitigated or the incident is over.

This is not an easy question since many factors influence how much hydrogen can be transferred from one vessel at a higher pressure to another one at a lower pressure and the rate at which it can be transferred. The pressure in the higher vessel will fall while that in the lower vessel will rise as gas is transferred, so the flow rate will typically slow down and eventually stop as the…

Category: Properties

It varies slightly due to different density of LH2 at different temperatures, but a gallon of LH2 at atmospheric pressure (0 psig) is ~113 SCF of H2. The expansion ratio is about 840:1. In metric units, a liter of LH2 at atmospheric pressure (0 MPa) would expand to about 840 liters of STP of gaseous pressure.

Category: Properties

The National Fire Protection Association (NFPA), the Compressed Gas Association (CGA), and the Society of Fire Protection Engineers (SFPE)   represent the U.S. fire protection and engineering community, and these organizations publish handbooks and standards/guidelines that describe the properties of hydrogen. There are many other organizations and documents that provide similar…

Category: Properties

This is an impossible question to answer without greater understanding of the quantities of hydrogen involved, the types of vessels involved, and the atmospheric conditions. Several companies offer software to model such releases. It’s important to note that there is a high probability of ignition either during the vessel rupture or from nearby ignition sources.

Category: Properties

Vaporization of a trapped volume of LH2 will lead to significant increase in pressure due to the very large expansion ratio as the liquid converts to gas. Relief devices are required since the pressure increase is likely to be far in excess of the pressure rating of the system. When vaporized as part of a flowing process, pressure will not increase. As the LH2 is warmed, it undergoes a phase…

Category: Properties

A pressure of 600 kPa (87 psi) is relatively moderate, so the combustion properties are similar to those at atmospheric pressure where the autoignition temperature of hydrogen is 585°C. 

Category: Properties

H2-air flammability limits vary with temperature  . The H2-air lower flammability limit is virtually the same as the H2-O2 lower limit. However, the H2-O2 upper flammability limit increases substantially to about 95% at room temperature and gets even higher at elevated temperatures.

Category: Properties
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