Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.

Requirements for TPRD/PRD’s depend on the local regulations. Some jurisdictions require them, some do not. Others make them optional based on results of performance testing.

This is a complicated subject. Thermally activated pressure relief devices can be an important safeguard for hydrogen vessels if properly designed and installed in accordance with code requirement. Requirements vary globally and often depend on the type of vessel and its intended service (e.g. mobile or stationary). However, as with any device, TPRD’s offer both advantages and disadvantages. System design, vessel location, surrounding exposures, other vessel protection options, type of vessel, consequences of a large release, and probability of inadvertent release are just a few of many parameters that should be considered.

Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.

In general, indoor storage should be limited and the use of hydrogen indoors should be the least necessary. Look to store flammable gases outdoors in dedicated protected area when practicable. Check to see what adopted building and fire codes in your jurisdiction say. NFPA 2, Hydrogen Technology Code, Sections 6.4.1 and 16.3 prescribe requirements to limit hydrogen storage and use in laboratories. NFPA also prescribes requirements for ventilation, gas cabinets, electrical classification, and fume hood operations. Consider outdoor or dedicated storage facilities if you need more than one standard-sized cylinder of hydrogen to support your work.

Outside storage is generally considered safer and is required for large amounts of gas. Stationary storage should be located outside at a safe distance from structures and ventilation intakes, and protected from vehicle impact. 

Hydrogen storage separation distance requirements are typically based on the quantity and pressure of the hydrogen or the piping diameter, depending on the type of storage. Consideration should be given to distances between multiple containers to prevent interaction during an unintended hydrogen release. More detailed guidance can be found in the applicable codes and standards such as NFPA 2, Hydrogen Technologies.

Nearly all hydrogen storage tanks and hydrogen storage systems will need some type of pressure relief system to protect the vessels from overpressure. If there are pressure relief devices, some means to vent the hydrogen to a safe location will be needed. An exception to this is hydrogen cylinders due to their relief device type (lead-backed rupture discs (CG-4/5) and
the need to transport them.

However, the nature of the devices and vent systems depends on the type, size, location, regulations, and pressure of the hydrogen tank, storage tubes, or tube trailers and related system. There may be other means to protect against overpressure or fire exposure, and there are situations where the risk of a release could exceed the risk posed by the relief device and
vent system. For example, many GH2 transportation trailers in the EU are not equipped with PRD’s or TPRD’s which are not required by local regulations. Ultimately the decision and design of vent systems is based upon a hazard assessment.

There are several levels of documents which can be used to assist with the design, sizing, selection, and installation of the pressure relief device settings for LH2 tanks. 

Pressure vessel design codes, such as the ASME Boiler and Pressure Vessel Code will provide minimum requirements for design of pressure vessels (including LH2 tanks), relief devices, and relief systems. However, these codes will not provide the sizing criteria nor anticipate all of the potential demand cases that might be imparted upon a vessel. 

In the US, the model fire codes require compliance with NFPA 2, which then references documents such as CGA S1.2 and CGA S1.3 for sizing criteria. These documents have been customized by the industrial gas business specifically for cryogenic fluids such as LH2. API Standard 520 “Sizing, Selection and Installation of Pressure-Relieving Devices in Refineries” of is also a helpful document to provide additional guidance. 

For LH2 storage tanks, usually the highest process demand is an engulfing fire with a loss of vacuum insulation to atmosphere. This failure mode can result in additional heat flux from air condensation in the annular space which must also be addressed. 

It is not required to proactively vent the contents of an LH2 tank when exposed to fire. Relief devices are required to prevent the accumulation of internal pressure to unsafe levels. Within the ASME BPV, this is 121% of Maximum Allowable Working Pressure for scenarios involving fire exposure. It is common practice, but not required, that at least one device be non-reclosing (e.g. a rupture disc) for both managing the high flow required as well as to relieve the contents of the tank. Reclosing relief devices will maintain pressure in a fire and are more likely to lead to a vessel rupture if the fire ultimately weakens the pressure vessel.

LH2 tanks are unlikely to BLEVE due to the vacuum insulation outer jacket (usually carbon or stainless steel) preventing direct impingement of fire onto the main pressure vessel, as well as the internal cryogenic contents maintaining the main pressure vessel walls at a cooler temperature until the contents have been relieved by the relief devices.