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Explosions - Electrolysis

Is there a list of earlier references to water alkaline H2 electrolysis explosions like the one at https://h2tools.org/lessons/water-electrolysis-system-explosion?

The lesson learned (LL) article referenced in the question cites an incident that occurred in December 1969. While there may have been other accidents, the HSP does not have any other LL articles on alkaline water electrolysis explosions. In the LL article that was updated in 2017, the technology described employs a potassium hydroxide (KOH) electrolyte solution. The KOH electrolyte is held by surface tension within a fibrous mat used as a cell separator. A 30 weight % KOH solution is typically circulated through each of many electrolysis cells internally manifolded together within a bipolar electrolysis cell stack. Product hydrogen with KOH solution rises into an overhead degassing tank (drum in the LL article); product oxygen with KOH solution rises into a separate overhead degassing tank. 

The article describes a breakdown of the separator allowing H2 and O2 gases to mix. Slight differences in pressure between the oxygen and hydrogen sides of the cell are enough to permit crossover of gases. A recent Gangwon electrolysis incident involved a semipermeable alkaline membrane technology instead of a fibrous cell separator. Conditions at near idle current may have allowed sufficient cross cell diffusion to occur, permitting an explosive mixture to collect in the storage tanks with the result reported. This event has not yet been published in our Hydrogen Tools LL database.

FAQ Category
Submission Year
2024
Month
04

Deflagrations-Water Sprays

Are there studies on how water spray affects hydrogen deflagration or detonation?

There is limited published research on the effect of water sprays on hydrogen deflagrations and deflagration-to-detonation transition, and more extensive data on water spray effects on hydrocarbon gas explosions. The results show the benefits, where there are benefits, to be highly scenario dependent. For example, Carlson et al. (Atomics International report, 1973) described hydrogen detonation tube testing with and without a 500-micrometer drop diameter water spray. They found the water spray prevented detonations at hydrogen concentrations of 20% to 24%, but not at 28%. Drop size is critical since the benefits of sprays depend on the droplets breaking up and partially vaporizing in advance of the propagating flame front. If the droplets do not break up, they induce turbulence effects that can significantly increase flame speeds and exacerbate hydrogen deflagrations. Both the detonation ability and deflagration scenarios are discussed in Technical Aspects of Hydrogen Control and Combustion in Severe Light-Water Reactor Accidents, National Academy Press, 1987. 

The effects of water deluge nozzle spray on methane and propane deflagrations in vented simulated offshore platform enclosures were investigated in Phase 2 (1998 report) of a European test program called Blast and Fire Engineering for Topside Structures. Comparisons of test results in highly obstructed enclosures with and without the deluge spray showed lower pressures with the deluge spray. However, the sprays did increase the initial flame speeds, which can be either good, if the flame induced velocities are large enough to cause droplet breakup, or bad, if the droplets remain intact. The authors conclude that deluge sprays prevent runaway flame acceleration in situations with inherently high flame speeds but will not be effective in applications where only low flame speeds are generated. Thus, the spray would be expected to be effective for near-stoichiometric H2-air mixtures, but detrimental for concentrations in the range of 8% to perhaps 13%.

FAQ Category
Submission Year
2024
Month
04

Testing – Explosion Prevention

Are there unique considerations when using foam and mesh technology to help prevent hydrogen explosions relative to other flammable gases?

No, but it is always necessary to determine the possibility of an adverse chemical reaction with the particular material being used for the mesh.

FAQ Category
Submission Year
2024
Month
04

Testing – Explosion Prevention

Has the Hydrogen Safety Panel had inquiries about metal mesh or polymer foam being used in composite or metal containers for hydrogen use as an explosion prevention system in accordance with NFPA 69?

The Panel has not received such inquiries. Section 14.2 of NFPA 69 Standard for Explosion Prevention Systems covers foam and mesh requirements. NFPA 69 states in 14.3.4 that the tests shall be conducted with a flammable gas/air mixture with a fundamental burning velocity representative of the burning velocities of flammable vapors expected in the intended applications.

FAQ Category
Submission Year
2024
Month
04

Testing – Explosion Prevention

What issues could arise from using hydrogen for explosion testing instead of propane?

Explosion testing with hydrogen should be utilized only where there is not an established alternative and then only by personnel experienced in such testing. 
Testing with hydrogen is always a challenge and needs to be approached carefully due to significant differences in properties between hydrogen and propane. Hydrogen can develop significantly higher overpressures and preliminary testing with leaner mixtures and possibly smaller containers should precede full-scale application tests. Documents such as NFPA 2, NFPA 68, and NFPA 60 provide additional guidance on the potential explosion hazards and properties of hydrogen.

FAQ Category
Submission Year
2024
Month
04

Explosion Mitigation

Can a wet mist system be used to prevent an H2 explosion? Is it considered experimental?

There are two parts for such a system to be effective. First, the system would have to activate quickly enough to establish a water mist throughout the region of interest (i.e., region occupied by a flammable gas mixture) before it could be ignited. This is challenging in terms of timing, and the impact of spraying water inside an enclosure filled with equipment not designed to get wet can be an issue. Second, such a system has to provide a sufficient density of water droplets in the right size range to have the desired effect. For conventional vapor cloud explosions (e.g., large vapor cloud occupying a portion of a process unit at a refinery or chemical plant), experimental work has examined the effect of water sprays. Getting a high enough density of the right sized water droplets has been shown to be effective at slowing the flame front, and hence reducing the resulting blast load. The goal has not been to put the flame out (i.e., quench the flame), as this would be much more difficult, but rather to absorb some of the combustion energy and hence slow the flame. 

The same type of research has been done for mine explosions in the U.S. For a hydrogen-air mixture inside an enclosure, it is theoretically possible to use a water spray (from a fast-acting system triggered on detection) to slow down the flame. This could reduce the demand on an explosion venting system or reduce the structural capacity required for a given vent system. There are a number of recent publications on this topic (i.e., slowing the flame front propagation velocity, reducing the maximum blast pressure, and/or extinguishing the flame for hydrogen or mixtures containing hydrogen). However, the HSP is not aware of any such system for hydrogen explosion prevention or mitigation in industrial applications being available for purchase. 

FAQ Category
Submission Year
2024
Month
04

Hydrogen Properties

What are good resources describing the properties of hydrogen?

The National Fire Protection Association (NFPA), the Compressed Gas Association (CGA), and the Society of Fire Protection Engineers (SFPE)   represent the U.S. fire protection and engineering community, and these organizations publish handbooks and standards/guidelines that describe the properties of hydrogen. There are many other organizations and documents that provide similar information. The Center for Hydrogen Safety within AIChE has training material for the properties and safe handling of hydrogen at the following link:

Fundamental Hydrogen Safety Credential 

FAQ Category
Submission Year
2024
Month
04
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