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Hydrogen Leak on a Fuel Cells Bus (972)

The event occurred in a bus garage when carrying out the purging process of the hydrogen cylinders. This process was executed via an electronic control system, but it was found that one cylinder solenoid valve was mechanically stuck. In these cases, the valve manufacturer has foreseen an alternative manual process using an override tool. The process was executed according to manufacturers instruction, but the valve did not start to evacuate hydrogen when expected. The fuel cell engineer tried to rectify the problem and started removing the override tool, but forgot to unwind the stem.

Hydrogen Release from a Gas Bottled in a R&D Laboratory (944)

A 50-litre standard hydrogen gas cylinder was temporarily placed and used in a laboratory. The hydrogen gas was used for a flame ionization detector (FID) in gas chromatography (GC) instrument. The safety relief valve on the pressure regulator blew open and released of about 340 g of hydrogen into a laboratory. The gas cloud did not ignite so there was no injury or damage. In Henriksen et al (see references) a full investigation is presented to verify the cause of leakage and estimate the gas concentration of the dispersion and gas cloud, including the modelling of a likely explosion.

Hydrogen Explosion on the Hydrogen Storage Facility of a Pharmaceutical Plant (898)

The event early on a Saturday morning, when the plant was thus practically empty. Nevertheless, the chronology of the accident can be reconstructed from the testimonies of the few operators who were present at the time:Phase 1: Gas leak - Loud whistling from the hydrogen storage facility could be heard , lasting 20 to 40 seconds.Phase 2: Explosion - The released hydrogen cloud ignites. A very bright, red-orange fireball measuring 15 to 20 m in diameter was visible for 3 minutes. Witnesses in a common room, located 100 m away from the pit, felt the shock wave and the heat from the blast.

Hydrogen Release and Ignition at the Gas Storage Station of a Nuclear Power Plant (890)

The accident took place when replacing a pallet of empty hydrogen cylinders with a new full one. The pallet in service (almost empty) was not disconnected from the gas supply line. When the operator in charge of handling (fork lift) begun to remove the pallet in service from its position, he teared off the hose connecting it to the pressure relief system. The pressurised hydrogen in the pipes and in the pallet escaped and ignited. The intervention of the teams from the plant and external emergency services extinguished the fire in 1h45.

Flask Explosion in Junior-High-School Science Experiment (862)

A triangle flask exploded during a science-class experiment where diluted hydrochloric acid was made to react with zinc to generate hydrogen, at a junior high school. Injures were caused by glass debris flown, five very lightly injured pupils were sent to hospital. Probably hydrogen entered in contact with oxygen because of a wrong experiment procedure, resulting in ignition and explosion.
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