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Pressure Vessel Failure in a Chemicals Plant (1045)

The vessel affected by the incident was a gas storage used for the desulfurisation process. The desulfurization gas had high hydrogen content. The vessels had cracks in the upper transverse fillet welds at the gas inlet which caused low stress brittle fractures. The cracks had been found during the maintenance, but not fixed. This eventually caused a gas release. Approximately 2.5 hours after that a leak was detected and reported, a first explosion occurred.

Explosion and Fire at a Diesel Hydrogenation Plant (1044)

The incident affected the raw material buffer tank (design pressure 0.38 MPa) of a diesel hydrogenation unit in a refinery. This buffer tank is located between the hydrogenation reactor and the raw material storage tank. During pressure fluctuations in the lubricating oil system of a hydrogen compressor, the operator handled the situation improperly, resulting in an abnormal shutdown of the compressor, causing the hydrogen feed pump to interlock and stop.After the pump interlocked, the outlet valve was not closed in time and the two check valves failed.

Explosion of a Flammable Mixture in a Petrochemical Plant (1042)

The incident occurred in a catalytic reforming unit. At 13:41, a leak occurred at the 90 elbow of a pressure pipe containing a mixture of hydrogen and naphtha. This pipe was located between the pre-hydrogenation heat exchanger and the pre-hydrogenation product tower heat exchanger. The flammable material leaking from the pipe burst into flames, and at 13:51 and 14:21 there were two more explosive combustions.

Leakage of Potassium Hydroxide from a Water Electrolyzer (1037)

The incident consisted of a leakage of potassium hydroxide solution (KOH) from an alkaline electrolyzer in a renewable hydrogen production plant. One webpage news reported that smoke formation triggered the fire alarm system. According to the manufacturer, the equipment shut down and automatically went into safety mode in accordance with the integrated safety system.Nobody was injured in the event and there was no damage on the environment.

Explosion of an Autoclave in a Laboratory (1033)

A researcher was conducting an experiment that involved sawdust being heated at pressure using hydrogen gas in an laboratory-scale autoclave.The gas leaked from the autoclave during the experiment and ignited, causing injuries to the scientist (cuts, bruises and facial burns).The explosion caused extensive damage to the building, propelling debris more than 20 metres into a garden area.

Explosion of a Hydrogen Pipeline (1027)

During agricultural drainage work carried out by a farmer, an explosion occurred on a hydrogen pipeline located in a field. Flames several meters high were visible and two houses were evacuated. A safety perimeter was set up. The pipeline operator applied procedures to ensure the safety of the local residents and the pipeline.The damaged pipe was listed by the operator. The farmer did not declare the work site and no verification was done before starting the work.[ARIA event 57406]
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