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Hazards Analysis, Storage

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Hazards Analysis, Storage
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Using tools inside a fume hood that may have a flammable gas mixture should be prohibited. A properly operating hood of the right capacity should keep the mixture of hydrogen in air inside the hood below the Lower Flammability Limit (LFL) of hydrogen further reducing any risk. 

If the use of tools is necessary, the source of hydrogen should be isolated before the work begins even if…

Category: Hazards Analysis
Keywords: Mixed Gas, Lower Flammability Limit (LFL), Leak, Spark-resistant

Frequency and severity off consequences are situational and subject to the safety review team’s best judgement. One measure of severity is an estimate of the energy released if ignited. Assuming the worst-case mix to be stoichiometric, the energy content of a 500 mL of hydrogen in air is about 0.2 Wh (700 Joules), comparable to the energy release of a wooden, blue-tipped matchstick (~1kJ or 1…

Category: Hazards Analysis
Keywords: Risk Assessment, Guidelines, Hazards Analysis

After moving people to a safe location, if it safe to do so, isolate the source of hydrogen feeding the fire. Burns and explosions are hazards when exposed to a hydrogen fire. For more best laboratory preventative safety practices as well as first responder response to a hydrogen incident See both CHS training resources: 

Category: Hazards Analysis
Keywords: Fire, Safety, First Responders, Training

Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.

Category: Storage
Keywords: Storage, Cylinder, Codes, NFPA 2, Guidelines

Static is a frequent source of ignition attributed to various hydrogen releases. Low levels of static
electricity are sufficient to ignite hydrogen – air mixtures. Static charges can be created by the
atmospheric disturbances and storms, high velocity particles entrained by the gas impacting stationary
objects, and human activity. Grounding of equipment and operators is important to…

Category: Hazards Analysis
Keywords: Static Charge, Ignition, Grounding

There is no consensus on the “correct” answer. Small leaks of short duration have a much lower
probability of ignition compared to large releases. Ignition probability is affected by the operating
conditions, whether the release is from a leak or vent stack, and the surrounding environment. Since the
probability of ignition is high, hazard analyses will usually assume the hydrogen…

Category: Hazards Analysis
Keywords: Release, Ignition Probability, Hazards Analysis, Risk Assessment

Releases from high pressure hydrogen systems often make a sound. In those cases, sound might be the
easiest way for a person to know there is a hazard. However, leaks can be relatively small and diffuse,
thereby not making much sound, or alternately large and so loud that they can be very difficult to find. In
both cases, it can be hazardous to move into or through an area.

Category: Hazards Analysis
Keywords: Flame, Sound Detection, Leak, High-pressure System

Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…

Category: Storage
Keywords: Leak, Vessel Design, Permeation, Emissions

Situations where extinguishing a hydrogen leak prior to stopping flow is safer are rare. Hydrogen releases have a high potential for inadvertent re-ignition and subsequent explosion. Some vent stacks might be equipped with an extinguishing system, but these often can be more hazardous than allowing a properly designed vent stack to continue to burn until the source is isolated.

Category: Hazards Analysis
Keywords: Fire, Extinguish, Re-ignition, Source Isolation

No, this is not a common or preferred approach. Isolating the source of hydrogen is the best safety practice. Water systems could extinguish the flame but allow the gas to continue leaking and result in an explosion if reignited.

Category: Hazards Analysis
Keywords: Facility, Deluge, Fire Protection, Explosion
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