NFPA 2 provides Tables in Chapters 7 and 8 that specify the hazardous area classifications surrounding vent stack outlets. These are based on typical vent systems and flows, but are only applicable for smaller systems. The designer of a vent system should apply the principles of documents such as IEC 60079-10-1 (also required by NFPA 2) or NFPA 497 to evaluate larger vent releases where the…

Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.

Guidance for location of vent stacks is provided by NFPA 2, Hydrogen Technologies Code, which also references CGA G5.5, Hydrogen Vent Systems, for additional guidance. Minimum distances to vent stack outlets should be determined from dispersion and radiation analyses. The height of the vent stack and orientation of the release will affect the minimum separation distance.

Dispersion and radiation analysis should be conducted to ensure that the hydrogen cloud will not interfere with the flight path of aircraft. In addition, there may be maximum height requirements due to airport requirements depending on the location of the stack.

Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…

Documents such as NFPA 2, Hydrogen Technologies Code, and the International Fire Code have quantity thresholds that differentiate requirements for the design of systems and enclosures. However, even the smaller quantities present a hazard under specific conditions, especially for systems that have the potential to release hydrogen into a confined or unvented space. Good engineering judgement…

Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.

Each installation should be evaluated based on the results of a hazard analysis considering both of these
scenarios. Separation distances as listed in documents such as NFPA 2, Hydrogen Technologies Code, are
a minimum starting point but may need to be adjusted based on analysis. Recent work by NFPA 2 has
also included overpressure criteria, but the consequences can vary depending on…

Each system should be evaluated for exposure of equipment to jet fires. The design team should develop
a plan to mitigate exposure as part of the hazard analysis. Fire barriers, walls, enclosures, and insulation
systems are frequently installed to meet code requirements where separation distances are not
sufficient or where the probability of exposure to a jet fire is high. Barriers…

Liquid hydrogen is much less likely to pool than liquified natural gas (LNG) due to its low heat of vaporization. Very large facilities are often equipped with methods to enhance vaporization, such as crushed stone under tanks, as well as diversion systems to allow liquid hydrogen to spill and boil off in a safe area. Care needs to be taken that diversion systems do not create a hazardous…