The interaction of single water droplet impacting on immiscible liquid surface was focused with the temperature varying from 50 degrees C to 210 degrees C. The impact behavior is recorded with a high-speed camera running at 2000 frames per second. It is found that droplet diameter, oil temperature, and Weber number have important influences on impact behaviors. Three typical phenomena, including penetration, crater-jet, and crater-jet-secondary jet, were observed. Penetration only occurs when the Weber number is below 105. With Weber number increasing to 302, the jet begins to appear. Moreover, to gain deeper physical insight into the crater formation and jet formation, the energy of droplet impingement onto the liquid pool surface was estimated. The oil temperature has a significant effect on the energy conversion efficiency. High temperature is beneficial to improve energy conversion efficiency.