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HIAD Specific Application Supply Chain Stage: Hydrogen As Process Gas


The incident occurred in a plant producing organic chemistry products. Hydrogen leaked briefly from an hydraulic valve. There has been no victim.
During the start-up operation (phase) of a cryogenic unit, a separator exploded, releasing ethane, ethylene, methane and hydrogen. The bursting of a tank was caused by a 1600 mm long incipient crack…
The event was initiated by the burst of a rupture disc on a reactor during a hydrogenation process. The hydrogenation reaction occurs under pressure in a tank containing 3,000 l of a mixture of…
The accident occurred on one of the heat exchangers of the hydro-desulfurisation unit. The role of the exchanger , located between the charge pumps and the furnace, is to heat the charge using the…
A leak of a flammable mixture of hydrocarbons and hydrogen from a ruptured pipeline caused an explosion and fire, killing one person and injuring forty six. Investigations into the incident found…
A release of contents of a pressure vessel occurred when a longitudinal weld tore open. The vessel had been shut down and had just been put into use again when the incident occurred.The gas mixture…
The leak occurred on the inlet pipe (P=21 bar, T=320C) of the diesel desulfurization reactor of a refinery. Hydrogen and diesel fuel were released in the gas phase. The hydrocarbons contaminates…
Although the ARIA report (see references) does not mention it, the unit affected was very probably the oil desulfurisation unit. The release occurred following the rupture of a pipe of 250 mm in…
Leakage of a mixture of hydrogen, nitrogen, citric, hydrofluoric and hydrogen sulfide occurs during ventilation shutdown on high temperature PVC furnaces. The accident follows an electrical outage…
The operator detected a leak of aerosol hydrocarbons (diesel, hydrogen and hydrogen sulfide) in the diesel desulfurisation unit, causing a release of hydrogen and hydrogen sulfide at the top of the…
The incident occurred in the hydrogenation reactor and products cooling unit. The reactor operated under vacuum conditions and the cooling medium was water.Toxic, flammable and explosive substances (…
A petroleum refinery experienced a catastrophic rupture of a heat exchanger in the catalytic reformer / naphtha hydrotreater unit (the NHT unit). The heat exchanger, catastrophically ruptured because…
A severe fire in a hydrogen compressor building in a unifier unit of an oil sands refinery reportedly started in a 1,500 psi lube oil system. Fire fighting was difficult because of 40 degrees F…
A short circuit developed in the wiring of a fire eye system on one of two 600 psig boilers serving a refinery. This triggered a rapid sequence of events that resulted in a one week shutdown of much…
Syngas explosion at a university laboratoryThe university lab affected was investigating generation of hydrogen and methane from biomass (wooden chips). The experimental furnace was a concrete…
A 24" pipe carrying synthesis gas (Hydrogen = 43.5%, Nitrogen = 14.08%, Methane = 0.2%, Carbon Dioxide = 12.3%, Water = 29.3% by volume) ruptured. About 60 kg of hydrogen contained in the gas…
The release of a blast furnace gas occurred at a section of pipework, due to the rupture of valve seal. The gas did not ignite and the fire service attended as a precaution. The gas was both…
A vertical cylindrical hydrodesulfurisation reactor charge heater was being started up with hydrogen flow only rather than hydrogen plus oil as in normal operation. As a result of the low heat load…
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