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The containerized electrolysis unit should be installed per manufacturer instructions, the requirements
of its listing such as to ISO 22734, Hydrogen generators using water electrolysis - Industrial, commercial,
and residential applications, and NFPA 2, Hydrogen Technologies Code. A primary consideration for
indoor installation is the potential for hydrogen releases from the system,…
The conversion is based on the condition as determined from a variety of non-destructive techniques which are commonly used for pipeline mechanical integrity programs. Existing natural gas pipelines are frequently evaluated for conversion to hydrogen, hydrogen-natural gas blend, and other fluid services.
The conversion can be done safely if handled with the proper expertise and…
Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.
The suspected cause was a mixture of oxygen and hydrogen that passed downstream from the electrolysis unit into several storage vessels. Hydrogen-oxygen mixtures are very hazardous. Subsequent ignition resulted in internal pressure that exceeded the limits of the storage system. The design of electrolyzers, detection of upset conditions, and preventing the accumulation of oxygen within the…
Hydrogen has been transported safely through pipelines for over 50 years. There are dozens of pipeline networks in safe operation globally, with several individual networks that approach up to 1000 miles.
Significant testing and some demonstration projects are underway to ensure safety. Some of the aspects under investigation include compatibility of the pipe and other materials,…
Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…
Acceptability of materials is highly dependent on the specific application. Applied stress levels, exposure to contaminants, the operating temperature, the partial pressure, and number and magnitude of material stress cycles are some of the factors that affect material selection. Guidance is provided within documents such as ISO 11114, Gas cylinders - Compatibility of cylinder and valve…
Because cast irons are relatively brittle materials, they should generally be avoided in industrial and
transmission pipeline applications. In low pressure applications like residential distribution piping
systems, the use of cast irons is probably acceptable.
Hydrogen affects the mechanical properties of most materials. For example, hydrogen reduces the
fracture toughness and increases the fatigue crack growth rate in steels. There is a significant amount of
research, analytical work, and codes and standards development being undertaken to improve our
understanding of how these materials can be utilized in pipelines. The results of the…
There is no maximum flow-rate that can be vented to the atmosphere, but the hazard analysis should consider the potential risk of dispersion, radiation, and overpressure as part of the vent system design. Flare systems are often used at large hydrogen production facilities as one means to prevent a large unignited cloud from forming but will depend on the specific application.
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