Cylinders used within a laboratory can be used safely by meeting the requirements prescribed in NFPA 2,
Hydrogen Technologies Code, and NFPA 45, Standard on Fire Protection for Laboratories Using Chemicals.
Special consideration should be given to both safe handling and storage of cylinders. Regarding lecture
size cylinders, their small size can make them susceptible to damage and…
Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.
Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…
Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.
Many methods are used to mitigate the risk of a tube trailer hose loss of containment incident. Examples that otherwise exceed code requirements are provided below. These have been deployed in various combinations depending on the risk analysis for a particular system:
A "drop and swap" delivery system using tube trailers is a common and accepted method of supply for both industrial and fueling station applications. While NFPA 2 - 2023, paragraph 10.6.3.5 states, "The use of hose in a hydrogen dispensing system shall be limited to vehicle fueling hose," this is intended for the dispenser itself, not the entire fueling station. This does not limit the use of…
Even if a small experiment is being run inside a fume hood, the best practice is to use a dedicated vent line for hydrogen which vents hydrogen to a safe location outside. This is especially recommended for planned venting. This practice avoids situations where flammable mixtures could develop. Each system is unique and should be evaluated and approved for use independently…
Gaseous hydrogen can be stored forever as long as the system integrity is maintained. However, liquid hydrogen is “use it or lose it” and will boil from system heat leak and build pressure unless it is used or vented. This is not usually an issue for continuous use or low-pressure applications which can use hydrogen gas pressure directly from the tank.
For intermittent or high…
Such a compressor should NOT be used for hydrogen. There are many issues with converting a compressor to hydrogen service. First and most important, this must be approved by the manufacturer. Examples of concerns for a non-hydrogen compressor used for hydrogen service include (but are not limited to):
Liquid hydrogen is much less likely to pool than liquified natural gas (LNG) due to its low heat of vaporization. Very large facilities are often equipped with methods to enhance vaporization, such as crushed stone under tanks, as well as diversion systems to allow liquid hydrogen to spill and boil off in a safe area. Care needs to be taken that diversion systems do not create a hazardous…
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