The “Hydrogen Ready Appliances Assessment Report” published by the Northwest Energy Efficiency Alliance (NEEA) in February, 2023, is one of the most recent studies on this topic.  Several key items from the report pertaining to this question include the following:

1.    “There appears to be growing consensus that blends of up to 20% or perhaps even 30% are…

The water vapor cloud formed from venting cold hydrogen gas from a liquid hydrogen tank will vary in size depending upon atmospheric conditions including ambient temperature and humidity. There is not a direct relationship between the water vapor cloud and the flammable could of hydrogen, but it’s often used as a proxy. 

Initially upon release, it is possible that H2 vapor from…

Yes, although not as common as high-pressure gas releases, high-velocity cold H2 gas has ignited during rupture disc and relief valve activation.

The purity required will be a function of the end use application. There are a variety of grades of hydrogen that can be purchased. The H2 purity will also vary based on source (GH2 or LH2) and production method. CGA G-5.3, Commodity Specification for Hydrogen, lists several typical purities of both liquid and gaseous hydrogen. Standard GH2 available from most suppliers is 99.95% hydrogen.…

A design condition for vent stacks is to always assume that the hydrogen will ignite. The stack musts be designed such that it can withstand those conditions as well as minimize radiation to surrounding personnel and exposures. Although hydrogen fires have comparatively low radiation compared to hydrocarbon fuels, the radiation from large releases from vent stacks can be quite high. Documents…

Several programs can predict this such as HyRAM or PHAST. The inputs are critical to a safe
answer.

This is not a simple answer due to the many types of flame lengths and flame orientations due to pressure and direction. NFPA 2 recommends that vent systems should be designed so that if the safety relief valve is relieving at capacity the radiative heat felt by an individual at grade…

Water icing at the exit of a stack is certainly an issue in cold climates. Significant effort has been put into vent stack outlet design to minimize the probability. Documents such as CGA G5.5 have topworks that are recommended. Stacks that face upward have a higher probability of having water, ice, or snow enter the stack and freeze. 

Delayed ignition is a significant hazard for hydrogen releases, either intended or unintended. The primary concern is the overpressure and energy release created from a vapor cloud which could contain a significant quantity of hydrogen. The H2Tools Incidents database contains a number of examples of delayed ignition. 

Absolutely. Vent systems will experience a variety of transient conditions of pressure, temperature, and thrust load, so stress analysis to anticipate the strength and flexibility needed are important for safe design. These issues are often overlooked and only become an issue when they are called upon to operate in emergencies. 

It is a best practice to include the vent system in…

There are many potential sources of delayed ignition. Hydrogen is easily ignited, and the larger the cloud, the more likely it is for it to find an ignition source. The cloud itself may serve as an ignition source as the force of the gas release may cause dust or other contaminants to mix in the air creating a static charge which ignites the hydrogen. Similarly, the force of the release can…