If the concentration of hydrogen is less than the Lower Flammability Limit (LFL) of 4% in an inert gas, it is unlikely that a leak of this gas mix will form a flammable mixture as it dilutes into air. For example, industry uses ‘forming gas’, a mixture of 4 to 5% H2 in nitrogen, as an oxide reducing agent in materials processing furnaces and soldering operations. This mixture can also be used…

The key concern with any hydrogen release is the risk of creating a flammable mixture. There should be no environmental issues if you properly vent hydrogen to a safe area where it is diluted in air below the flammability limit before contacting an ignition source. Very small quantities of hydrogen are frequently releasing into a fume hood. Releases have to be small enough so that the vent air…

Using tools inside a fume hood that may have a flammable gas mixture should be prohibited. A properly operating hood of the right capacity should keep the mixture of hydrogen in air inside the hood below the Lower Flammability Limit (LFL) of hydrogen further reducing any risk. 

If the use of tools is necessary, the source of hydrogen should be isolated before the work begins even if…

Frequency and severity off consequences are situational and subject to the safety review team’s best judgement. One measure of severity is an estimate of the energy released if ignited. Assuming the worst-case mix to be stoichiometric, the energy content of a 500 mL of hydrogen in air is about 0.2 Wh (700 Joules), comparable to the energy release of a wooden, blue-tipped matchstick (~1kJ or 1…

After moving people to a safe location, if it safe to do so, isolate the source of hydrogen feeding the fire. Burns and explosions are hazards when exposed to a hydrogen fire. For more best laboratory preventative safety practices as well as first responder response to a hydrogen incident See both CHS training resources: 

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Static is a frequent source of ignition attributed to various hydrogen releases. Low levels of static
electricity are sufficient to ignite hydrogen – air mixtures. Static charges can be created by the
atmospheric disturbances and storms, high velocity particles entrained by the gas impacting stationary
objects, and human activity. Grounding of equipment and operators is important to…

There is no consensus on the “correct” answer. Small leaks of short duration have a much lower
probability of ignition compared to large releases. Ignition probability is affected by the operating
conditions, whether the release is from a leak or vent stack, and the surrounding environment. Since the
probability of ignition is high, hazard analyses will usually assume the hydrogen…

Hydrogen affects the mechanical properties of most materials. For example, hydrogen reduces the
fracture toughness and increases the fatigue crack growth rate in steels. There is a significant amount of
research, analytical work, and codes and standards development being undertaken to improve our
understanding of how these materials can be utilized in pipelines. The results of the…

Because cast irons are relatively brittle materials, they should generally be avoided in industrial and
transmission pipeline applications. In low pressure applications like residential distribution piping
systems, the use of cast irons is probably acceptable.

Acceptability of materials is highly dependent on the specific application. Applied stress levels, exposure to contaminants, the operating temperature, the partial pressure, and number and magnitude of material stress cycles are some of the factors that affect material selection. Guidance is provided within documents such as ISO 11114, Gas cylinders - Compatibility of cylinder and valve…