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There are dozens of safety considerations for safe design of hydrogen vent stacks. Their primary function
is to vent the hydrogen safely, so vent stacks should be designed such that the gas dispersion and
radiation profile (if ignited) do not impact surrounding equipment, buildings, or people. Documents such
as CGA G5.5, Hydrogen Vent Systems, provide numerous details regarding design…

Category: System Design

There is no consensus on the “correct” answer. Small leaks of short duration have a much lower
probability of ignition compared to large releases. Ignition probability is affected by the operating
conditions, whether the release is from a leak or vent stack, and the surrounding environment. Since the
probability of ignition is high, hazard analyses will usually assume the hydrogen…

Electrolyzers should be installed per manufacturer recommendations and meet the criteria of their
listing, such as ISO 22734, Hydrogen generators using water electrolysis - Industrial, commercial, and
residential applications. There are several methods such as partitions, enclosures, ventilation, and
purging that can be used to address non-classified electrical equipment.

Category: System Design

Static is a frequent source of ignition attributed to various hydrogen releases. Low levels of static
electricity are sufficient to ignite hydrogen – air mixtures. Static charges can be created by the
atmospheric disturbances and storms, high velocity particles entrained by the gas impacting stationary
objects, and human activity. Grounding of equipment and operators is important to…

Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.

Category: Storage

Flare-less compression style fittings are commonly used. Choose tubing materials and tube wall thicknesses suitable for hydrogen and pressures you are using. Make sure all tubing joints are properly made, mechanically supported to minimize stress and vibration, are in a ventilated space, and are easily accessible for inspection and leak testing. 

Category: Miscellaneous
Keywords: Tubing, Guidelines

After moving people to a safe location, if it safe to do so, isolate the source of hydrogen feeding the fire. Burns and explosions are hazards when exposed to a hydrogen fire. For more best laboratory preventative safety practices as well as first responder response to a hydrogen incident See both CHS training resources: 

Frequency and severity off consequences are situational and subject to the safety review team’s best judgement. One measure of severity is an estimate of the energy released if ignited. Assuming the worst-case mix to be stoichiometric, the energy content of a 500 mL of hydrogen in air is about 0.2 Wh (700 Joules), comparable to the energy release of a wooden, blue-tipped matchstick (~1kJ or 1…

Using tools inside a fume hood that may have a flammable gas mixture should be prohibited. A properly operating hood of the right capacity should keep the mixture of hydrogen in air inside the hood below the Lower Flammability Limit (LFL) of hydrogen further reducing any risk. 

If the use of tools is necessary, the source of hydrogen should be isolated before the work begins even if…

The key concern with any hydrogen release is the risk of creating a flammable mixture. There should be no environmental issues if you properly vent hydrogen to a safe area where it is diluted in air below the flammability limit before contacting an ignition source. Very small quantities of hydrogen are frequently releasing into a fume hood. Releases have to be small enough so that the vent air…

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