The ignition of a hydrogen-air mixture that has engulfed a typical set of ambient vaporizers (i.e., an array of finned tubes) may result in a deflagration-to-detonation transition (DDT). Simplified curve-based vapor cloud explosion (VCE) blast load prediction methods, such as the Baker-Strehlow-Tang (BST) method, would predict a DDT given that typical ambient vaporizerswould be rated as medium or high congestion and hydrogen is a high reactivity fuel (i.e., high laminar burning velocity).

Natural gas was first used as a vehicle fuel as far back as the 1930s. The first natural gas vehicles, which ran on uncompressed natural gas, were called “gas bag” vehicles and were used to combat gasoline shortages during World War I [1]. During and after World War II, compressed natural gas (CNG) vehicles using fuel tanks mounted on the roof gained popularity in France and Italy [2]. Today, there are more than 24 million CNG vehicles in service worldwide, including CNG buses that continue the early tradition of mounting fuel tanks on the roof.  

The HSP has reviewed many safety plans for gaseous hydrogen. An emerging trend is the use of liquid (cryogenic) hydrogen in the commercial market, potentially near residential areas, for fueling hydrogen fuel cell vehicles. Finding a “qualified” person to determine liquid hydrogen code compliance is difficult, and the skills necessary of such an individual are not well defined in the codes and standards.

Hydrogen Safety Panel, Safety Knowledge Tools, and First Responder Training Resources 

PNNL’s Hydrogen Safety ProgramWhy Hydrogen Fuel?Hydrogen – A Clean, Flexible Energy CarrierWhy Fuel Cells? H2@scale: Enabling Affordable, Reliable, Clean, and Secure Energy Across SectorsUpward trend with global fuel cell shipments 2018 U.S. Snapshot More details in Slides

Introduce the Hydrogen Safety Panel (HSP)Introduce key hydrogen safety resources that are availableOpen discussion on your hydrogen safety issues and needsExplore how the HSP can help the safe rollout of hydrogen and fuel cell technologiesIdentify projects that could utilize the HSP for impactful safety reviews

Ammonia and hydrogen represent opposite ends of the spectrum with regard to the potential blast loading resulting from an accidental vapor cloud explosion (VCE), although many in industry have expressed doubts as to whether either of these fuels actually pose a VCE hazard. Ammonia is some-times discounted as a VCE hazard due to the perceived difficulty in igniting an ammonia-air mixture and/or because of its low laminar burning velocity. Hydrogen is sometimes discounted as a VCE hazard due to the ease with which a hydrogen-air mixture can be ignited and/or because of its buoy-ancy.

The purpose of this guide is to assist users of codes and standards that apply to hydrogen application and use in understanding and applying the approval, certification, listing, and labeling provisions of the codes and standards, in any application where the required certification, listing, and labeling of services, methods, or equipment has not yet been established or achieved.  

VIII.6  Hydrogen Safety Panel, Safety Knowledge Tools and First Responder Training Resources

Video of how cryogenic system work.  Especially for LH2 for HSP