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Abstract

The future widespread use of hydrogen as an energy carrier brings in safety issues that have to be addressed before public acceptance can be achieved. The prediction of the consequences of a major accident release of hydrogen into the atmosphere or the contamination of high-pressure hydrogen storage facilities by air entrainment requires a good knowledge of the explosion parameters of hydrogen-air mixtures. The present paper reviews and comments on the current knowledge of dynamic parameters of hydrogen detonation for hazard assessment. The major problem that remains to be resolved involves the understanding of the effect of turbulence on the cellular detonation structure, the propagation of high-speed deflagrations and the transition from deflagration to detonations. It is recommended that future research should be aimed towards experiments that permit the quantitative understanding of the mechanisms of high-speed turbulent combustion rather towards large-scale tests in complex geometries where minimal quantitative information of fundamental significance could be extracted. In spite of its wide flammability and sensitivity to ignition and detonation initiation, it is felt that hydrogen can be produced, stored and handled safely with the appropriate considerations in the design of the hydrogen facilities. (C) 2007 Elsevier Ltd. All rights reserved.

Year of Publication
2008
Journal
Journal of Loss Prevention in the Process Industries
Volume
21
Number of Pages
136-146
ISBN Number
0950-4230
Accession Number
WOS:000254766300003
DOI
10.1016/j.jlp.2007.06.001
Alternate Journal
J Loss Prevent Proc
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