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Materials for piping hydrogen and hydrogen mixtures

What materials are suitable for piping hydrogen and hydrogen mixtures? Are there any guides or references available for selecting piping and fittings for hydrogen applications?

In laboratories, 316 stainless steel tubing is frequently the first choice for small flow and pressures less than 2800 psi (19 MPa). See Best Practices: Material Compatibility for hydrogen compatibility with various materials. Always work within manufacturer’s pressure ratings adjusted for temperature. Read and follow manufacturer’s instructions on making up tubing fittings, avoid threaded fittings, and properly purge with nitrogen, helium or other inert gas to remove air before introducing hydrogen.

FAQ Category
Submission Year
2023
Month
09

Pipe Connections

Can compression fittings for 304 or 316 SS tubing that use compressive forces to swage the fitting on onto tubing be used? The fitting is made for up to three pieces. One concern is the potential for hydrogen embrittlement in the area around the joint compression as the pipe is under large stresses when the joint is made. There is a video on how this works at the link below, starting at ~ 2 min 20 secs. (437) The Lokring High Performance Connector System - YouTube

The HSP is not familiar with this particular fitting or its potential application in H2 service but can offer engineering judgment. Many similar compression-type swaged fittings are used in H2 service. These fittings must be used within the manufacturer recommendations for pressure, temperature, and fluid service. Deformation is also introduced into stainless steel tubing in other ways, such as creating bends, but these locations are not reported to be more vulnerable to failure in H2 service provided that they are within an acceptable range.   

This is probably 300-series stainless steels, particularly 316, that are resistant to hydrogen embrittlement under static stress, although cyclic stresses add the potential for hydrogen-assisted fatigue cracking. One area of caution when applying the fitting to 304 piping is the potential to form strain-induced martensite (phase with magnetic signature) in the stainless steel. The martensite phase is more susceptible to hydrogen embrittlement than the surrounding matrix, and a widely recognized best practice is to limit the formation of these phases with magnetic signature for stainless steels in hydrogen gas service.


As with all compression-style fittings, there is a significant risk of incorrect or incomplete installation. Examples include failure to install the ferrules, installation of the ferrules in the wrong order or backwards, incomplete insertion, and incomplete tightening to reach the proper swaging of the tubing to ensure the necessary grip at high pressure. Fittings should always be inspected, either visually or with appropriate tools, and pressure tested prior to putting into service.
 

FAQ Category
Submission Year
2024
Month
04

Cylinder Connections

Are there generic best practices for connecting hydrogen cylinders to research equipment? The project in question uses single H2 cylinders outside of a gas cylinder cabinet. When and where should an excess flow control valve be installed? When and where should a flash arrestor be installed? Are there specific things to look out for when a hydrogen and oxygen or oxidizer cylinder (i.e., nitrous oxide) are on the same system? What kind of cross connections should be avoided? When and where should there be a check valve installed? Can quick connects be used on hydrogen tubing? Are there specific pressure regulators to select or avoid with hydrogen? When and where should purge valves be installed? What are the recommended valve and regulator components of a H2/O2 torch assembly?

It is difficult to provide trustworthy answers to these questions without understanding the design and configuration of the specific installation. It may be best to consult with a pressure systems expert to evaluate the specific installation and uses. The gas provider may also be a good resource for specifics on gas equipment use. Other beneficial resources include the HSP Best Practices online resource and the DOE Hydrogen Safety Training for Researchers, the AIChE Laboratory Safety Course.

NFPA 2, Hydrogen Technologies Code, and NFPA 45, Standard on Fire Protection for Laboratories Using Chemicals, may also be helpful in identifying requirements and best practices. In addition, the project designed should consult with the local authority having jurisdiction for safety guidance that is applicable to locally adopted codes.
 

FAQ Category
Submission Year
2024
Month
04
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