Catalytic recombiners are effective at preventing flammable hydrogen mixtures and also sometimes useful to monitor hydrogen concentrations through heat evolution when an oxidizer is present. Careful considerations must be made when integrating these elements into a design, so that they do not become a source ignition (and/or flame arrestors prevent propagation of a flame front) and the…

Typically, the inner vessel material used is 304 SS and the outer vessel is a combination of 304 SS and carbon steel depending on location. 316 SS or 316L material can be used, but due to higher cost and lower strength, are typically only used for higher purity systems. Nearly all tanks manufactured today use various forms of vacuum jacketed multilayer insulation for best performance. Older…

A design condition for vent stacks is to always assume that the hydrogen will ignite. The stack musts be designed such that it can withstand those conditions as well as minimize radiation to surrounding personnel and exposures. Although hydrogen fires have comparatively low radiation compared to hydrocarbon fuels, the radiation from large releases from vent stacks can be quite high. Documents…

The most common means to warm liquid or cold gaseous hydrogen is the use of ambient air vaporizers using ambient atmospheric. Other means can be through the use of electric heat or process waste heat.  

The purity required will be a function of the end use application. There are a variety of grades of hydrogen that can be purchased. The H2 purity will also vary based on source (GH2 or LH2) and production method. CGA G-5.3, Commodity Specification for Hydrogen, lists several typical purities of both liquid and gaseous hydrogen. Standard GH2 available from most suppliers is 99.95% hydrogen.…

The pressure regulator controls the liquid flow from the tank to the pressure build (PB) vaporizer. As the tank pressure falls, the pressure regulator opens. When the set pressure of the regulator is reached, then the regulator closes. The pressure build circuit depends largely on the required use pressure and the system house-line pressure drop, which is driven by peak flow rate, pressure,…

A pressure gauge is not usually provided, as one set of devices (safety valve and rupture disc) is always online by design. If the diverter valve connecting the two sets of relief devices is in the center position, both sets are online although depending upon the design of the diverter valve, it might not allow full flow in either direction. For the secondary stack with a rupture disc and a…

Yes, although not as common as high-pressure gas releases, high-velocity cold H2 gas has ignited during rupture disc and relief valve activation.

The water vapor cloud formed from venting cold hydrogen gas from a liquid hydrogen tank will vary in size depending upon atmospheric conditions including ambient temperature and humidity. There is not a direct relationship between the water vapor cloud and the flammable cloud of hydrogen, but it’s often used as a proxy. 

Initially upon release, it is possible that H2 vapor from…

As is mentioned in the question, it should always be assumed that vent stack fires will occur. The vent stack must be designed to withstand a possible deflagration and the heat from a continuous vent stack fire. The stack should also have sufficient height and be located such that thermal radiation is safe for surrounding personnel, equipment, and buildings. The codes and standards have…