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Most common odorants will contaminate fuel cells. Additionally, hydrogen's small molecule and high buoyancy make it challenging to find a compatible odorant. Research is being conducted on fuel cell compatible odorants, but there are none currently in use. Like liquefied natural gas, liquid hydrogen also can’t be odorized due to its cryogenic temperature.
Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.
Requirements for TPRD/PRD’s depend on the local regulations. Some jurisdictions require them, some do not. Others make them optional based on results of performance testing.
This is a complicated subject. Thermally activated pressure relief devices can be an important safeguard for hydrogen vessels if properly designed and installed in accordance with code requirement. Requirements vary globally and often depend on the type of vessel and its intended service (e.g. mobile or stationary). However, as with any device, TPRD’s offer both advantages and disadvantages.…
Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…
Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.
Hydrogen flames can be nearly invisible in daylight, especially at low flowrates. The concentration of hydrogen does not have much effect on the color of the flame. Many hydrogen incidents or fires will have a bright orange hue, or even yellow flames. The color is primarily caused by contaminants that is either naturally in the air in certain environments, swept into the air during the release…
Yes, small flowrate vents may be invisible, particularly in daylight. Sometimes it may still be possible to see heat striations in the air from the heat generated by the fire, but it can be difficult to discern at low flowrates.
Relief device sizing for liquid hydrogen tanks follow recognized standards such as CGA S1.3. The sizing criteria include a worst-case scenario of an engulfing fire with loss of vacuum integrity.
LH2 tanks are unlikely to BLEVE due to the vacuum insulation outer jacket (usually carbon or stainless steel) preventing direct impingement of fire onto the main pressure vessel, as well as the…
There are several levels of documents which can be used to assist with the design, sizing, selection, and installation of the pressure relief device settings for LH2 tanks.
Pressure vessel design codes, such as the ASME Boiler and Pressure Vessel Code will provide minimum requirements for design of pressure vessels (including LH2 tanks), relief devices, and relief systems. However…
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