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Yes, these would be ignitable mixtures. In this case, it does not appear complicated geometry is involved, so 1200 psig pipe should be more than adequate to protect against internal deflagration. The most likely scenario is a "backfire," similar to a car, where ignition occurs too soon and shoots out the open end of the pipe. Consider using an inline deflagration flash arrestor on the…
1. As of January 2024, we are not aware of any public data on incidents or investigations where a hydrogen fired steam boiler exploded.
2. The potential for detonations within a boiler tube would depend on both the equivalence ratio of the hydrogen present and the diameter of the boiler tube.
a. At a minimum, if the circumference of the tube is…
Several organizations published a paper together on this topic in 2017 (see attached). Based on comparisons with tests and CFD simulations, the following conclusions were drawn:
Store flammable gas cylinders such as hydrogen, separated from oxidizing (e.g. oxygen), toxic, pyrophoric, corrosive, and reactive Class 2, 3, or 4 gases. Non-reactive gases, such as helium, may be co-located. See codes and standards such as NFPA 2 [7.2.1.1 Incompatible Materials] for further guidance.
Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…
Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.
Liquid hydrogen is much less likely to pool than liquified natural gas (LNG) due to its low heat of vaporization. Very large facilities are often equipped with methods to enhance vaporization, such as crushed stone under tanks, as well as diversion systems to allow liquid hydrogen to spill and boil off in a safe area. Care needs to be taken that diversion systems do not create a hazardous…
By definition, liquid hydrogen can BLEVE, but this is highly unlikely. Liquid hydrogen is stored in a double wall tank with vacuum insulation. This protects the primary pressure vessel from direct impingement and the very cold liquid provides self-cooling of the vessel walls. Tanks are also equipped with redundant pressure relief systems that are sized for fire exposure.
Underground storage tanks can be either installed in a vault or directly buried. Both offer additional
protection from external impact and fire, but each has unique challenges. Vaults must be properly
ventilated and designed to not create an explosion or asphyxiation risk. Direct burial vessels should not
have any underground leak points and must be protected from corrosion. Both…
This can be a complex problem and response to insulation failure should be considered in the emergency response guidelines and procedures.
First, a tank with an insulation failure may boil off at an elevated rate which applicable codes build into the relief device and vent system design.
Second, ice and oxygen enriched liquefied air can form where inadequately insulated surfaces…
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