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Explosions, Pressure Relief Devices, Properties

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Explosions, Pressure Relief Devices, Properties

Most common odorants will contaminate fuel cells. Additionally, hydrogen's small molecule and high buoyancy make it challenging to find a compatible odorant. Research is being conducted on fuel cell compatible odorants, but there are none currently in use. Like liquefied natural gas, liquid hydrogen also can’t be odorized due to its cryogenic temperature.

Category: Properties
Keywords: Odorant, Odor

Requirements for TPRD/PRD’s depend on the local regulations. Some jurisdictions require them, some do not. Others make them optional based on results of performance testing.

This is a complicated subject. Thermally activated pressure relief devices can be an important safeguard for hydrogen vessels if properly designed and installed in accordance with code requirement. Requirements vary globally and often depend on the type of vessel and its intended service (e.g. mobile or stationary). However, as with any device, TPRD’s offer both advantages and disadvantages.…

Hydrogen flames can be nearly invisible in daylight, especially at low flowrates. The concentration of hydrogen does not have much effect on the color of the flame. Many hydrogen incidents or fires will have a bright orange hue, or even yellow flames. The color is primarily caused by contaminants that is either naturally in the air in certain environments, swept into the air during the release…

Category: Properties
Keywords: Fire, Flame

Yes, small flowrate vents may be invisible, particularly in daylight. Sometimes it may still be possible to see heat striations in the air from the heat generated by the fire, but it can be difficult to discern at low flowrates. 

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Keywords: Vent, Flame, Flow

Relief device sizing for liquid hydrogen tanks follow recognized standards such as CGA S1.3. The sizing criteria include a worst-case scenario of an engulfing fire with loss of vacuum integrity.

LH2 tanks are unlikely to BLEVE due to the vacuum insulation outer jacket (usually carbon or stainless steel) preventing direct impingement of fire onto the main pressure vessel, as well as the…

Several organizations published a paper together on this topic in 2017 (see attached). Based on comparisons with tests and CFD simulations, the following conclusions were drawn:

  1. The gas concentration for vapor cloud explosion blast load calculations for H2 jets can be limited to approximately 10% to 75%. Note that testing for H2-air VCEs in congested environments has been performed…
Category: Explosions

There are several levels of documents which can be used to assist with the design, sizing, selection, and installation of the pressure relief device settings for LH2 tanks. 

Pressure vessel design codes, such as the ASME Boiler and Pressure Vessel Code will provide minimum requirements for design of pressure vessels (including LH2 tanks), relief devices, and relief systems. However…

Safety codes globally have a requirement to provide a positive means to isolate energy sources and hazardous substances prior to performing maintenance. For gaseous hydrogen systems, methods such as a blind flange, a double block valve arrangement or a double block and bleed valve arrangement can provide that positive isolation.

Installing a blind flange requires breaking the supply line…

Keywords: Valves, Codes

Pressure relief systems may use reclosing devices like relief valves, non-reclosing devices like rupture discs, or a combination of both in parallel. Some systems may also be equipped with emergency blowdown systems that are operated by control systems. Selection of the proper devices is dependent on the system design and relative hazards. Variables that affect the selection include the type…

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